Citation: Cheng-hua Cui, Ding-xiang Yan, Huan Pang, Li-chuan Jia, Yu Bao, Xin Jiang, Zhong-ming Li. Towards Efficient Electromagnetic Interference Shielding Performance for Polyethylene Composites by Structuring Segregated Carbon Black/Graphite Networks[J]. Chinese Journal of Polymer Science, ;2016, 34(12): 1490-1499. doi: 10.1007/s10118-016-1849-6 shu

Towards Efficient Electromagnetic Interference Shielding Performance for Polyethylene Composites by Structuring Segregated Carbon Black/Graphite Networks

College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China

Corresponding author: Ding-xiang Yan, yandingxiang@scu.edu.cn
Received Date: 16 June 2016
Revised Date: 21 July 2016
Accepted Date: 25 July 2016

Fund Project: the National Natural Science Foundation of China 51120135002the China Postdoctoral Science Foundation 2016T90848the National Natural Science Foundation of China 51473102the China Postdoctoral Science Foundation 2015M572474the National Natural Science Foundation of China 51421061the Innovation Team Program of Science and Technology Department of Sichuan Province 2014TD0002

An electromagnetic interference (EMI) shielding composite based on ultrahigh molecular weight polyethylene (UHMWPE) loaded with economical graphite-carbon black (CB) hybrid fillers was prepared via a green and facile methodology, i.e., high-speed mechanical mixing combined with hot compression thus avoiding the assistance of the intensive ultrasound dispersion in volatile organic solvents. In this composite, the graphite-CB hybrid fillers were selectively distributed in the interfacial regions of UHMWPE domains resulting a typical segregated structure. Thanks to the specific morphology of segregated conductive networks along with the synergetic effect of large-sized graphite flakes and small-sized CB nanoparticles, a low filler loading of 7.7 vol% (15 wt%) yielded the graphite-CB/UHMWPE composites with a satisfactory electrical conductivity of 33.9 S/m and a superior shielding effectiveness of 40.2 dB, manifesting the comparable value of the pricey large-aspect-ratio carbon nanofillers (e.g., carbon nanotubes and graphene nanosheets) based polymer composites. More interestingly, with the addition of 15 wt% graphite-CB (1/3, W/W) hybrid fillers, the tensile strength and elongation at break of the composite reached 25.3 MPa and 126%, respectively; with a remarkable increase of 58.1% and 2420% over the conventional segregated graphite/UHMWPE composites. The mechanical reinforcement could be attributed to the favor of the small-sized CB particles in the polymer molecular diffusion between UHMWPE domains which in turn provided a stronger interfacial adhesion. This work provides a facile, green and affordable strategy to obtain the polymer composites with high electrical conductivity, efficient EMI shielding, and balanced mechanical performance.
- Graphite,
- Carbon black,
- Segregated structure,
- Electromagnetic interference,
- Synergistic effect
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