Citation: Yi-ren Tang, Ting Li, Hai-mu Ye, Jun Xu, Bao-hua Guo. The Effect of Polymer-Substrate Interaction on the Nucleation Property: Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets[J]. Chinese Journal of Polymer Science, ;2016, 34(8): 1021-1031. doi: 10.1007/s10118-016-1816-2 shu

The Effect of Polymer-Substrate Interaction on the Nucleation Property: Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets

Yi-ren Tang ^a ,
Ting Li ^a ,
Hai-mu Ye ^b ,
Jun Xu ^a,, ,
Bao-hua Guo ^a,,

a.
Advanced Materials Laboratory of Ministry of Education, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
b.
Department of Materials Science and Engineering, China University of Petroleum, Beijing 102249, China

Corresponding author: Jun Xu, jun-xu@mail.tsinghua.edu.cn Bao-hua Guo, bhguo@mail.tsinghua.edu.cn
Received Date: 14 February 2016
Revised Date: 14 March 2016
Accepted Date: 14 March 2016

Fund Project: the National Natural Science Foundation of China 51473085the National Natural Science Foundation of China 21374054This work was financially supported by the National Basic Research Program of China 2014CB932202

Hexagonal boron nitride nanosheets (BNNSs) can work as a more efficient nucleating agent for two polyesters compared to graphene. Studies on the crystallization and dewetting processes of two polyesters, poly(butylene succinate) and poly(butylene adipate), on the two substrate surfaces prove that the interaction between BNNSs and the polyesters is stronger than that between graphene and the polyesters. This strong interaction induces the pre-ordered conformation of molten PBA which has been identified by the in situ FTIR spectra. Thus BNNSs possess higher nucleation property than graphene. Finally, a new polymer-substrate interaction induced nucleation mechanism was proposed to explain the nucleation efficiency difference between graphene and BNNSs.
- Hexagonal boron nitride nanosheets,
- Graphene,
- Crystallization,
- Dewetting,
- Interaction
1. [1]
  Chen, J.B., Xu, J.Z., Xu, H., Li, Z.M., Zhong, G.J. and Lei, J., Chinese J. Polym. Sci., 2015, 33(4):576 doi: 10.1007/s10118-015-1608-0
2. [2]
  Ye, H.M., Wang, R.D., Liu, J., Xu, J. and Guo, B.H., Macromolecules, 2012, 45:5667 doi: 10.1021/ma300685f
3. [3]
  Pan, P.J., Yang, J.J., Shan, G.R., Bao, Y.Z., Weng, Z.X. and Inoue, Y., Macromol. Mater. Eng., 2012, 297:670 doi: 10.1002/mame.v297.7
4. [4]
  Dong, T., Kai, W.H. and Inoue, Y., Macromolecules, 2007, 40:8285 doi: 10.1021/ma071776o
5. [5]
  Leng, J.H., Liu, H., He, B.B., Yang, B., Chen, X. and Qin, Q.Q., Chinese J. Polym. Sci., 2013, 31(11):1563 doi: 10.1007/s10118-013-1311-y
6. [6]
  Sun, Y.J., Li, H.H., Huang, Y., Chen, E.Q., Zhao, L.F., Gan, Z.H. and Yan, S.K., Macromolecules, 2005, 38:2739 doi: 10.1021/ma0474269
7. [7]
  Guo, X.J., Liu, H.Z., Zhang, J.W. and Huang, J.J., Ind. Eng. Chem. Res., 2014, 53:4869
8. [8]
  Lopes, A.C., Costa, C.M., Tavares, C.J., Neves, I.C. and Mendez, S.L., J. Phys. Chem. C., 2011, 115:180762
9. [9]
  Yang, B., Ni, H.K., Huang, J.J. and Luo, Y., Macromolecules, 2013, 47:284
10. [10]
  Legras, R., Mercier, J.P. and Nield, E., Nature, 1983, 304:432 doi: 10.1038/304432a0
11. [11]
  Wittmann, J.C. and Lotz, B., Prog. Polym. Sci., 1990, 15:909 doi: 10.1016/0079-6700(90)90025-V
12. [12]
  Wittmann, J.C. and Lotz, B., Polym. Sci., Polym. Phys. Ed., 1981, 19:1837 doi: 10.1002/pol.1981.180191204
13. [13]
  Xin, R., Zhang, J., Sun, X.L., Li, H.H., Qiu, Z.B. and Yan, S.K., Adv. Polym. Sci., 2015, DOI:10.1007/12_2015_329 doi: 10.1007/12_2015_329
14. [14]
  Yan, S.K., Bonnet, M. and Petermann, J., Polymer, 2000, 41:1139 doi: 10.1016/S0032-3861(99)00243-8
15. [15]
  Wu, Z.Q., Wang, G., Zhang, M.W., Wang, K. and Fu, Q., Soft Matter, 2016, 12:594 doi: 10.1039/C5SM02030A
16. [16]
  Tang, Y.R., Gao, Y., Xu, J. and Guo, B.H., CrystEngComm, 2015, 17:6467 doi: 10.1039/C5CE01175B
17. [17]
  Balandin, A.A., Ghosh, S., Bao, W.Z., Calizo, I., Teweldebrhan, D., Miao, F. and Lau, C.N., Nano Lett., 2008, 8:902 doi: 10.1021/nl0731872
18. [18]
  Lee, C., Wei, X.D., Kysar, J.W. and Hone, J., Science, 2008, 321:385 doi: 10.1126/science.1157996
19. [19]
  Zhang, Y.B., Tan, Y.W., Stormer, H.L. and Kim, P., Nature, 2005, 438:201 doi: 10.1038/nature04235
20. [20]
  Cheng, S., Chen, X., Hsuan, Y.G. and Li, C.Y., Macromolecules, 2011, 45:993
21. [21]
  Wang, B.J., Zhang, Y.J., Zhang, J.Q., Li, H.Y., Chen, P., Wang, Z.B. and Gu, Q., Ind. Eng. Chem. Res., 2013, 52:15824 doi: 10.1021/ie402062j
22. [22]
  Sano, M., Sasaki, D.Y. and Kunitake, T., Science, 1992, 258:441 doi: 10.1126/science.258.5081.441
23. [23]
  Jiang, Z.N. and Qiu, Z.B., RSC Adv., 2015, 5:55486 doi: 10.1039/C5RA10332K
24. [24]
  Wang, G.S., Wei, Z.Y., Sang, L., Chen, G.Y., Zhang, W.X., Dong, X.F. and Qi, M., Chinese J. Polym. Sci., 2013, 31(8):1148 doi: 10.1007/s10118-013-1278-8
25. [25]
  Pang, H., Zhong, G.J., Xu, J.Z., Yan, D.X., Ji, X., Li, Z.M. and Chen, C., Chinese J. Polym. Sci., 2012, 30(6):879 doi: 10.1007/s10118-012-1170-y
26. [26]
  Nag, A., Raidongia, K., Hembram, K.P.S.S., Datta, R., Waghmare, U.V. and Rao, C.N.R., ACS Nano, 2010, 4:1539 doi: 10.1021/nn9018762
27. [27]
  Tang, Y.R., Lin, D.W, Gao, Y., Xu, J. and Guo, B.H., Ind. Eng. Chem. Res., 2014, 53:4689 doi: 10.1021/ie403915j
28. [28]
  Wang, X.W., Zhang, C.A., Wang, P.L., Zhao, J., Zhang, W. and Ji, J.H., Langmuir, 2012, 28:7091 doi: 10.1021/la204894h
29. [29]
  Du, X.C., Wang, Y.P., Huang, W.B., Yang, J.H. and Wang, Y., Colloid. Polym. Sci., 2015, 293:389 doi: 10.1007/s00396-014-3428-0
30. [30]
  Tang, Y.R., Xu, J. and Guo, B.H., Ind. Eng. Chem. Res., 2015, 54:1832 doi: 10.1021/ie504593z
31. [31]
  Park, S.J., An, J.H., Piner, R.D., Jung, I., Yang, D.X., Velamakanni, A., Nguyen, S.T. and Ruoff, R.S., Chem. Mater., 2008, 20:6592 doi: 10.1021/cm801932u
32. [32]
  Pei, S.F., Zhao, J.P., Du, J.H., Ren, W.C. and Cheng, H.M., Carbon, 2010, 48:4466 doi: 10.1016/j.carbon.2010.08.006
33. [33]
  Owen, M.J., J. Appl. Polym. Sci., 1988, 35:895 doi: 10.1002/app.1988.070350405
34. [34]
  Tong, Y., Lin, Y., Wang, S.D. and Song, M., Polymer, 2015, 73:52 doi: 10.1016/j.polymer.2015.07.025
35. [35]
  Frömsdorf, A., Woo, E.M., Lee, L.T., Chen, Y.F. and Fröster, S., Macromol. Rapid Commun., 2008, 29:1322 doi: 10.1002/marc.v29:15
36. [36]
  Zhao, L.F., Wang, X.H., Li, L. and Gan, Z.H., Polymer, 2007, 48:6152 doi: 10.1016/j.polymer.2007.07.055
37. [37]
  Liu, J., Ye, H.M., Xu, J. and Guo, B.H., Polymer, 2011, 52:4619 doi: 10.1016/j.polymer.2011.08.001
38. [38]
  Sun, X.L., Chen, Z., Wang, F., Yan, S.K. and Takahashi, I., Macromolecules, 2013, 46:1573 doi: 10.1021/ma302349a
39. [39]
  Rafiee, J., Mi, X., Gullapalli, H., Tomas, A.V., Yavari, F., Shi, Y.F., Ajayan, P.M. and Koratkar, N.A., Nat. Mater., 2012, 11:217 doi: 10.1038/nmat3228
40. [40]
  Li, Q., Zhou, J.D., Chai, L.G., Memon, J., Ren, Z.J., Li, H.H., Sun, X.L. and Yan, S.K., Polym. Chem., 2014, 5:4293 doi: 10.1039/c4py00119b
41. [41]
  Zhou, J.D., Gan, H.Y., Ren, Z.J., Li, H.H., Zhang, J.M., Sun, X.L. and Yan, S.K., Polymer, 2014, 55:5821 doi: 10.1016/j.polymer.2014.09.018
42. [42]
  Song, Y.Y., Ye, H.M., Meng, X.Y., Zhou, Q. and Lu, G.W., RSC Adv, 2015, 5:102384 doi: 10.1039/C5RA19099A
43. [43]
  Yang, J.J., Li, Z.G., Pan, P.J., Zhu, B., Dong, T. and Inoue, Y., J. Polym. Sci., Part B:Polym. Phys., 2009, 47:1997 doi: 10.1002/polb.v47:20
44. [44]
  Yan, C., Zhang, Y., Hu, Y., Ozaki, Y., Shen, D.Y., Gan, Z.H., Yan, S.K. and Takahashi, I., J. Phys. Chem. B., 2008, 112:3311
45. [45]
  Hamieh, M., Akhrass, S.Al., Hamieh, T., Damman, P., Gabriele, S., Vilmin, T., Raphaël, E. and Reiter, G., J. Adhes., 2007, 83:367 doi: 10.1080/00218460701282497
46. [46]
  Han, X., Luo, C.Y., Dai, Y.Y. and Liu, H.L., J. Macromol. Sci. B., 2008, 47:1050 doi: 10.1080/00222340802266322
47. [47]
  Brochard-Wyart, F., Debregeas, G., Fondecave, R. and Martin, P., Macromolecules, 1997, 30:1211 doi: 10.1021/ma960929x
48. [48]
  Vitt, E. and Shull, K.R., Macromolecules, 1995, 28:6349 doi: 10.1021/ma00122a049
49. [49]
  Schonhorn, H., Macromolecules, 1968, 1:145 doi: 10.1021/ma60002a008
50. [50]
  Chen, X.M., Zhang, L.Y., Park, C., Fay, C.C., Wang, X.Q. and Ke, C.H., Appl. Phys. Lett., 2015, 107:253105 doi: 10.1063/1.4936755
51. [51]
  Li, L.Y., Li, C.Y. and Ni, C.Y., J. Am. Chem. Soc., 2006, 128:1692 doi: 10.1021/ja056923h
52. [52]
  Xu, J.Z., Chen, T., Yang, C L, Li, Z.M., Mao, Y.M., Zeng, B.Q. and Hsiao, B.S., Macromolecules, 2010, 46:5000
53. [53]
  Yan, C., Li, H.H., Zhang, J.M., Ozaki, Y., Shen, D.Y., Yan, D.D., Shi, A.C. and Yan, S.K., Macromolecules, 2006, 39:8041 doi: 10.1021/ma061188v
1. [1]
  Yarui Li , Huangjie Lu , Yingzhe Du , Jie Qiu , Peng Lin , Jian Lin . Highly efficient separation of high-valent actinide ions from lanthanides via fractional crystallization. Chinese Journal of Structural Chemistry, 2025, 44(4): 100562-100562. doi: 10.1016/j.cjsc.2025.100562
2. [2]
  Wenjing Xiong , Yulin Xu , Fangzhou Zhao , Baokai Xia , Hongqiang Wang , Wei Liu , Sheng Chen , Yongzhi Zhang . Graphene architecture interpenetrated with mesoporous carbon nanosheets promotes fast and stable potassium storage. Chinese Chemical Letters, 2025, 36(4): 109738-. doi: 10.1016/j.cclet.2024.109738
3. [3]
  Yuwen Zhu , Xiang Deng , Yan Wu , Baode Shen , Lingyu Hang , Yuye Xue , Hailong Yuan . Formation mechanism of herpetrione self-assembled nanoparticles based on pH-driven method. Chinese Chemical Letters, 2025, 36(1): 109733-. doi: 10.1016/j.cclet.2024.109733
4. [4]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
5. [5]
  Sanmei Wang , Yong Zhou , Hengxin Fang , Chunyang Nie , Chang Q Sun , Biao Wang . Constant-potential simulation of electrocatalytic N₂ reduction over atomic metal-N-graphene catalysts. Chinese Chemical Letters, 2025, 36(3): 110476-. doi: 10.1016/j.cclet.2024.110476
6. [6]
  Sanmei Wang , Dengxin Yan , Wenhua Zhang , Liangbing Wang . Graphene-supported isolated platinum atoms and platinum dimers for CO₂ hydrogenation: Catalytic activity and selectivity variations. Chinese Chemical Letters, 2025, 36(4): 110611-. doi: 10.1016/j.cclet.2024.110611
7. [7]
  Caili Yang , Tao Long , Ruotong Li , Chunyang Wu , Yuan-Li Ding . Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors. Chinese Chemical Letters, 2025, 36(2): 109675-. doi: 10.1016/j.cclet.2024.109675
8. [8]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
9. [9]
  Wenhao Yan , Shuaiya Xue , Xuerui Zhao , Wei Zhang , Jian Li . Hexagonal boron nitride based slippery liquid infused porous surface with anti-corrosion, anti-contaminant and anti-icing properties for protecting magnesium alloy. Chinese Chemical Letters, 2024, 35(4): 109224-. doi: 10.1016/j.cclet.2023.109224
10. [10]
  Jun Lu , Jinrui Yan , Yaohao Guo , Junjie Qiu , Shuangliang Zhao , Bo Bao . Controlling solid form and crystal habit of triphenylmethanol by antisolvent crystallization in a microfluidic device. Chinese Chemical Letters, 2024, 35(4): 108876-. doi: 10.1016/j.cclet.2023.108876
11. [11]
  Zhibin Ren , Shan Li , Xiaoying Liu , Guanghao Lv , Lei Chen , Jingli Wang , Xingyi Li , Jiaqing Wang . Penetrating efficiency of supramolecular hydrogel eye drops: Electrostatic interaction surpasses ligand-receptor interaction. Chinese Chemical Letters, 2024, 35(11): 109629-. doi: 10.1016/j.cclet.2024.109629
12. [12]
  Cheng Wang , Ji Wang , Dong Liu , Zhi-Ling Zhang . Advances in virus-host interaction research based on microfluidic platforms. Chinese Chemical Letters, 2024, 35(12): 110302-. doi: 10.1016/j.cclet.2024.110302
13. [13]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
14. [14]
  Yan-Bo Li , Yi Li , Liang Yin . Copper(Ⅰ)-catalyzed diastereodivergent construction of vicinal P-chiral and C-chiral centers facilitated by dual "soft-soft" interaction. Chinese Chemical Letters, 2024, 35(7): 109294-. doi: 10.1016/j.cclet.2023.109294
15. [15]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
16. [16]
  Tian Cao , Xuyin Ding , Qiwen Peng , Min Zhang , Guoyue Shi . Intelligent laser-induced graphene sensor for multiplex probing catechol isomers. Chinese Chemical Letters, 2024, 35(7): 109238-. doi: 10.1016/j.cclet.2023.109238
17. [17]
  Rui Liu , Jinbo Pang , Weijia Zhou . Monolayer water shepherding supertight MXene/graphene composite films. Chinese Journal of Structural Chemistry, 2024, 43(10): 100329-100329. doi: 10.1016/j.cjsc.2024.100329
18. [18]
  Yueying Wang , Jianming Xiong , Linwei Xin , Yuanyuan Li , He Huang , Wenjun Miao . Photosensitizer-synergized g-carbon nitride nanosheets with enhanced photocatalytic activity for eradicating drug-resistant bacteria and promoting wound healing. Chinese Chemical Letters, 2025, 36(4): 110003-. doi: 10.1016/j.cclet.2024.110003
19. [19]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
20. [20]
  Ying Chen , Li Li , Junyao Zhang , Tongrui Sun , Xuan Zhang , Shiqi Zhang , Jia Huang , Yidong Zou . Tailored ionically conductive graphene oxide-encased metal ions for ultrasensitive cadaverine sensor. Chinese Chemical Letters, 2024, 35(8): 109102-. doi: 10.1016/j.cclet.2023.109102

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(799)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142