Citation: Juan Liu, Xin Lu, Zhong Xin, Chang-lu Zhou. Surface Properties and Hydrogen Bonds of Mono-functional Polybenzoxazines with Different N-substituents[J]. Chinese Journal of Polymer Science, ;2016, 34(8): 919-932. doi: 10.1007/s10118-016-1810-8 shu

Surface Properties and Hydrogen Bonds of Mono-functional Polybenzoxazines with Different N-substituents

School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

Corresponding author: Zhong Xin, xzh@ecust.edu.cn
Received Date: 4 February 2016
Revised Date: 4 March 2016
Accepted Date: 7 March 2016

Fund Project: This work was financially supported by the Nanotech Foundation of Science and Technology Commission of Shanghai Municipality 0652nm001the National Natural Science Fundation of China u1162110the Fundamental Research Funds for the Central Universities WA1514015China Postdoctoral Science Foundation 2015M571509

A series of mono-functional benzoxazine monomers with different N-substituents were synthesized from phenol, formaldehyde, and various amines (ammonia, methylamine, n-butylamine, dodecylamine), named P-am, P-m, P-b, and P-da, respectively. The surface properties of these polybenzoxazine films were proven by contact angle measurements. The hydrogen bond network of the polybenzoxazine systems was studied using the FTIR spectra. And the results showed that the surface free energy increased with increasing the fraction of intermolecular hydrogen bonding when the N-substituent was an alkyl chain. However, the rule was not suitable when the N-substituent was H. That was because there was one more kind of intramolecular hydrogen bond in the poly(P-am). Based on these findings, we proposed that both the N-substituent alkyl group and the fraction of intermolecular hydrogen bonding had effects on the surface free energy.
- Polybenzoxazine,
- Mono-functional,
- N-substituents,
- Surface free energy,
- Hydrogen bonding
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