Morphology Evolution, Conductive and Viscoelastic Behaviors of Chemically Reduced Graphene Oxide Filled Poly(methyl methacrylate)/Poly(styrene-co-acrylonitrile) Nanocomposites during Annealing

Citation: Chao-ying Lin, Min Zuo, Hui-hui Li, Ting Liu, Qiang Zheng. Morphology Evolution, Conductive and Viscoelastic Behaviors of Chemically Reduced Graphene Oxide Filled Poly(methyl methacrylate)/Poly(styrene-co-acrylonitrile) Nanocomposites during Annealing[J]. Chinese Journal of Polymer Science, 2015, 33(8): 1162-1175. doi: 10.1007/s10118-015-1666-3 shu

Morphology Evolution, Conductive and Viscoelastic Behaviors of Chemically Reduced Graphene Oxide Filled Poly(methyl methacrylate)/Poly(styrene-co-acrylonitrile) Nanocomposites during Annealing

1.
MOE Key Laboratory of Macromolecule Synthesis and Functionalization, Ministry of Education, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

通讯作者: Min Zuo,

基金项目:
This work was financially supported by the National Natural Science Foundation of China (Nos. 51273173 and 51003093) and the Research Foundation of Education Bureau of Zhejiang Province (No. Y200908238).

摘要: The effect of chemically reduced graphene oxide (CRGO) on the phase separation behavior of poly(methyl methacrylate)/poly(styrene-co-acrylonitrile) (PMMA/SAN) blends and the simultaneous response of rheological and conductive behavior of PMMA/SAN/CRGO nanocomposites upon annealing above the phase-separation temperatures were investigated. The introduction of CRGO causes the decrease of binodal temperature and the increase of spinodal temperature for PMMA/SAN blends and then enlarges their metastable regime. During annealing, the well-dispersed CRGO in the homogeneous blend matrix tends to be selectively located in the SAN-rich phase with the evolution of phase separation and then the CRGO further agglomerates effectively in the SAN-rich phase to form the conductive pathway. Thermal-induced dynamic percolation is observed for both the resistivity and dynamic storage modulus G' as a function of annealing time. The resistivity variation is ascribed to the agglomeration of CRGO in the SAN-rich phase, while the modulus evolution is attributed to the combined contribution of phase separation for blend matrix and the agglomeration of CRGO in the SAN-rich phase.

关键词:

English

Morphology Evolution, Conductive and Viscoelastic Behaviors of Chemically Reduced Graphene Oxide Filled Poly(methyl methacrylate)/Poly(styrene-co-acrylonitrile) Nanocomposites during Annealing

1.
MOE Key Laboratory of Macromolecule Synthesis and Functionalization, Ministry of Education, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Min Zuo,

Received Date: 30 December 2014
Revised Date: 20 January 2015
Available Online: 05 August 2015
Fund Project:
This work was financially supported by the National Natural Science Foundation of China (Nos. 51273173 and 51003093) and the Research Foundation of Education Bureau of Zhejiang Province (No. Y200908238).

Abstract: The effect of chemically reduced graphene oxide (CRGO) on the phase separation behavior of poly(methyl methacrylate)/poly(styrene-co-acrylonitrile) (PMMA/SAN) blends and the simultaneous response of rheological and conductive behavior of PMMA/SAN/CRGO nanocomposites upon annealing above the phase-separation temperatures were investigated. The introduction of CRGO causes the decrease of binodal temperature and the increase of spinodal temperature for PMMA/SAN blends and then enlarges their metastable regime. During annealing, the well-dispersed CRGO in the homogeneous blend matrix tends to be selectively located in the SAN-rich phase with the evolution of phase separation and then the CRGO further agglomerates effectively in the SAN-rich phase to form the conductive pathway. Thermal-induced dynamic percolation is observed for both the resistivity and dynamic storage modulus G' as a function of annealing time. The resistivity variation is ascribed to the agglomeration of CRGO in the SAN-rich phase, while the modulus evolution is attributed to the combined contribution of phase separation for blend matrix and the agglomeration of CRGO in the SAN-rich phase.

Key words:

1. [1]
  Wu, G., Asai, S., Zhang, C., Miura, T. and Sumita, M., J. Appl. Phys., 2000, 88(3): 1480
2. [2]
  Norman, R.M., Conductive rubbers and plastics, Elsevier, New York, 1970, p. 12
3. [3]
  Krishnamoorti, R. and Vaia, R.A., Polymer nanocomposites, American Chemical Society, Washington, 2002, p. 89
4. [4]
  Noel, N., Faucheu, J., Chenal, J.M., Viricelle, J.P. and Bourgeat-Lami, E., Polymer, 2014, 55(20): 5140
5. [5]
  Xu, C.F., Tan, Y.Q., Song, Y.H. and Zheng, Q., Polym. Int., 2013, 62(2): 238
6. [6]
  Dai, K., Li, Z.M. and Xu, X.B., Polymer, 2008, 49(4): 1037
7. [7]
  Hopkins, A.R. and Reynolds, J.R., Macromolecules, 2000, 33(14): 5221
8. [8]
  Gubbels, F., Jerome, R., Teyssie, P., Vanlathem, E., Deltour, R., Calderone, A., Parente, V. and Bredas, J.L., Macromolecules, 1994, 27(7): 1972
9. [9]
  Meincke, O., Kaempfer, D., Weickmann, H., Friedrich, C., Vathauer, M. and Warth, H., Polymer, 2004, 45(3): 739
10. [10]
  Bose, S., Bhattacharyya, A.R., Khare, R.A., Kamath, S.S. and Kulkarni, A.R., Polym. Eng. Sci., 2011, 51(10): 1987
11. [11]
  Poyekar, A.V., Bhattacharyya, A.R., Panwar, A.S., Simon, G.P. and Sutar, D.S., ACS Appl. Mater. Inter., 2014, 6(14): 11054
12. [12]
  Postschke, P., Bhattacharyya, A.R. and Janke, A., Polymer, 2003, 44(26): 8061
13. [13]
  Gao, J.F., Huang, H.D., Yan, D.X., Ren, P.G., Zeng, X.B. and Li, Z.M., J. Macromol. Sci., B, 2013, 52(6): 788
14. [14]
  Yui, H., Wu, G.Z., Sano, H., Sumita, M. and Kino, K., Polymer, 2006, 47(10): 3599
15. [15]
  Zhang, S.M., Deng, H., Zhang, Q. and Fu, Q., ACS Appl. Mater. Inter., 2014, 6(9): 6835
16. [16]
  Gao, X., Zhang, S.M., Mai, F., Lin, L., Deng, Y., Deng, H. and Fu, Q., J. Mater. Chem., 2011, 21(17): 6401
17. [17]
  Dai, K., Xu, X.B. and Li, Z.M., Polymer, 2007, 48(3): 849
18. [18]
  Li, B., Zhang, Y.C., Li, Z.M., Li, S.N. and Zhang, X.N., J. Phys. Chem., B, 2009, 114(2): 689
19. [19]
  Gao, J.F., Yan, D.X., Yuan, B., Huang, H.D. and Li, Z.M., Compos. Sci. Technol., 2010, 70(13): 1973
20. [20]
  Fenouillot, F., Cassagnau, P. and Majeste, J., Polymer, 2009, 50(6): 1333
21. [21]
  Nesterov, A.E., Lipatov, Y.S., Horichko, V.V. and Gritsenko, O.T., Polymer, 1992, 33(3): 619
22. [22]
  Li, W., I'Abee, R.M.A, and Goossens, J.G.P., Macromol. Chem. Phys., 2013, 214(23): 2705
23. [23]
  Lipatov, Y.S., Nesterov, A.E., Ignatova, T.D. and Nesterov, D.A., Polymer, 2002, 43(3): 875
24. [24]
  Ginzburg, V.V., Macromolecules, 2005, 38(6): 2362
25. [25]
  Zhu, Y.W., Murali, S., Cai, W.W., Li, X.S., Suk, J.W., Potts, J.R. and Ruoff, R,S., Adv. Mater., 2010, 22(35): 3906
26. [26]
  Rao, C.N.R., Sood, A.K., Subrahmanyam, K.S. and Govindaraj, A., Angew. Chem. Int. Ed., 2009, 48(42): 7752
27. [27]
  Dai, G. and Mishnaevsky Jr, L., Compos. Mater. Sci., 2014, 95: 684
28. [28]
  Aguilar-Bolados, H., Brasero, J., Lopez-Manchado, M.A. and Yazdani-Pedram, M., Compos. Part B: Eng., 2014, 67: 449
29. [29]
  You, F., Wang, D., Cao, J., Li, X., Dang, Z.M. and Hu, G.H., Polym. Int., 2014, 63(1): 93
30. [30]
  Ramanathan, T., Abdala, A.A., Stankovich, S., Dikin, D.A., Herrera-Alonso, M., Piner, R.D., Adamson, D.H., Schniepp, H.C., Chen, X.. Ruoff, R.S., Nguyen, S.T., Aksay, I.A., Prud'homme, R.K. and Brinson, L.C., Nature Nanotechnol., 2008, 3(6): 327
31. [31]
  Kim, H., Abdala, A.A. and Macosko, C.W., Macromolecules, 2010, 43(16): 6515
32. [32]
  Vleminckx, G., Bose, S., Leys, J., Vermant, J., Wbbenhorst, M., Abdala, A.A., Macosko, C. and Moldenaers, P., ACS Appl. Mater. Inter., 2011, 3(8): 3172
33. [33]
  Zheng, Q. and Zuo, M., Chinese J. Polym. Sci., 2005, 23(4): 341
34. [34]
  Cassagnau, P., Polymer, 2008, 49(9): 2183
35. [35]
  Wu, G., Lin, J., Zheng, Q. and Zhang, M.Q., Polymer, 2006, 37(7): 2442
36. [36]
  Payne, A.R., J. Appl. Polym. Sci., 1965, 9(3): 1073
37. [37]
  Voet, A. and Cook, F.R., Rubber Chem. Technol., 1968, 41(5): 1207
38. [38]
  Pan, X.D. and Mckinley, G.H., Langmuir, 1998, 14(5): 985
39. [39]
  Liu, Z.H., Song, Y.H., Zhou, J.F. and Zheng, Q., J. Mater. Sci., 2007, 42(20): 8757
40. [40]
  Liu, Z.H., Song, Y.H., Shangguan, Y.G. and Zheng, Q., J. Mater. Sci., 2007, 42(8): 2903
41. [41]
  Liu, Z.H., Song, Y.H., Shangguan, Y.G. and Zheng, Q., J. Mater. Sci., 2008, 43(14): 4828
42. [42]
  Zhou, J.F., Song, Y.H., Shangguan, Y.G. and Zheng, Q., J. Appl. Polym. Sci., 2008, 110(4): 2001
43. [43]
  Hummers, W.S. and Offeman, R.E., J. Am. Chem. Soc., 1958, 80(6): 1339
44. [44]
  Kovtyukhova, N.I., Ollivier, P.J., Martin, B.R., Mallouk, T.E., Chizhik, S.A., Buzaneva, E.V. and Gorchinskiy, A.D., Chem. Mater., 1999, 11(3): 771
45. [45]
  Tan, Y.Q., Song, Y.H. and Zheng, Q., Nanoscale, 2012, 4(22): 6997
46. [46]
  Ramirez, C. and Osendi, M.I., Ceram. Int., 2014, 40(7): 11187
47. [47]
  Wang, S., Zhang, Y., Abidi, N. and Cabrales, L., Langmuir, 2009, 25(18): 11078
48. [48]
  Song, Y., Cao, Q. and Zheng, Q., Colloid Polym. Sci., 2012, 290(17): 1837
49. [49]
  Cao, Q., Song, Y., Tan, Y. and Zheng, Q., Polymer, 2009, 50(26): 6350
50. [50]
  Alig, I,, Skipa, T., Lellinger, D. and Potschke, P., Polymer, 2008, 49(16): 3524
51. [51]
  Hobbie, E.K., Sanghoon, A.K. and Han, C.C., Phys. Rev. E, 1996, 54(6): R5909
52. [52]
  Du, M., Wu, Q., Zuo, M. and Zheng, Q., Eur. Polym. J., 2013, 49(9): 2721
53. [53]
  Gao, J.P., Huang, C.W., Wang, N., Yu, W. and Zhou, C.X., Polymer, 2012, 53(8): 1772
54. [54]
  Jones, R.A.L., Laura J., Kramer, E.J., Bates, F.S. and Wiltzius, P., Phys. Rev. Lett., 1991, 66(17): 1326
55. [55]
  Yang, H.H., Han, C.D. and Kim, J.K., Polymer, 1994, 35(7): 1503
56. [56]
  Niu, Y.H. and Wang, Z.G., Macromolecules, 2006, 39(12): 4175
57. [57]
  Sharma, K., Sharma, M., Chandra, A. and Bose, S., Macromol. Chem. Phys., 2013, 214(23): 2651
58. [58]
  Fredrickson, G.H. and Larson, R.G., J. Chem. Phys., 1987, 86(3): 1553
59. [59]
  Castro, M., Prochazka, F. and Carrot, C., J. Rheol., 2005, 49(1): 149
60. [60]
  Huang, C.W., Gao, J.P., Yu, W. and Zhou, C.X., Macromolecules, 2012, 45(20): 8420
61. [61]
  Gharachorlou, A. and Goharpey, F., Macromolecules, 2008, 41(9): 3276
62. [62]
  Xia, Q.M., The preparation and properties of CNT/LDPE/PS conductive composites, Thesis, Donghua University, 2007
63. [63]
  Bose, S., Cardinaels, R., zdilek, C., Leys, J., Seo W.J., Wbbenhorst, M. and Moldenaers, P., Eur. Polym. J., 2014, 53(1): 253
64. [64]
  Sumita, M., Sakata, K., Asai, S., Miyasaka, K. and Nakagawa, H., Polym. Bull., 1991, 25(1): 265
65. [65]
  Wu, S., J. Polym. Sci. Polym. Symp., 1971, 34(1): 19
66. [66]
  Souteng, W., Polymer interface and adhesion, Marcel Dekker, New York, 1982
67. [67]
  Pand, D.Z., Zuo, M., Zhao, J.S. and Zheng, Q., Chinese J. Polym. Sci., 2013, 31(11): 1470
68. [68]
  Wu, G.Z., Asai, S. and Sumita, M., Macromolecules, 2002, 35(5): 1708
69. [69]
  Zuo, M. and Zheng, Q., Macromol. Chem. Phys., 2006, 207(21): 1927
70. [70]
  Polios, I.S., Soliman, M., Lee, C., Gido, S.P., Schmidt-Rohr, K. and Winter, H.H., Macromolecules, 1997, 30(15): 4470
71. [71]
  Bar-Chaput, S. and Carrot, C., Rheol. Acta, 2006, 45(4): 339
72. [72]
  Cao, Q., Song. Y.H., Tan, Y.Q. and Zheng, Q., Carbon, 2010, 48(15): 4268
73. [73]
  Cassagnau, Ph. and Melis, F., Polymer, 2003, 44(21): 6607
74. [74]
  Tan, Y.Q., Song Y.H., Cao, Q. and Zheng, Q., Polym. Int., 2011, 60(5): 823

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 2091
HTML全文浏览量: 60

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Morphology Evolution, Conductive and Viscoelastic Behaviors of Chemically Reduced Graphene Oxide Filled Poly(methyl methacrylate)/Poly(styrene-co-acrylonitrile) Nanocomposites during Annealing

通讯作者: Min Zuo,

English

Morphology Evolution, Conductive and Viscoelastic Behaviors of Chemically Reduced Graphene Oxide Filled Poly(methyl methacrylate)/Poly(styrene-co-acrylonitrile) Nanocomposites during Annealing

Corresponding author: Min Zuo,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Morphology Evolution, Conductive and Viscoelastic Behaviors of Chemically Reduced Graphene Oxide Filled Poly(methyl methacrylate)/Poly(styrene-co-acrylonitrile) Nanocomposites during Annealing

通讯作者: Min Zuo,

English

Morphology Evolution, Conductive and Viscoelastic Behaviors of Chemically Reduced Graphene Oxide Filled Poly(methyl methacrylate)/Poly(styrene-co-acrylonitrile) Nanocomposites during Annealing

Corresponding author: Min Zuo,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs