Solvent Property Induced Morphological Changes of ABA Amphiphilic Triblock Copolymer Micelles in Dilute Solution: A Self-consistent Field Simulation Study

Juan-juan Fan ,  Yuan-yuan Han ,  Jie Cui

Citation:  Juan-juan Fan, Yuan-yuan Han, Jie Cui. Solvent Property Induced Morphological Changes of ABA Amphiphilic Triblock Copolymer Micelles in Dilute Solution: A Self-consistent Field Simulation Study[J]. Chinese Journal of Polymer Science, 2014, 32(12): 1704-1713. doi: 10.1007/s10118-014-1529-3 shu

Solvent Property Induced Morphological Changes of ABA Amphiphilic Triblock Copolymer Micelles in Dilute Solution: A Self-consistent Field Simulation Study

    通讯作者: Jie Cui, jcui@ciac.jl.cn
  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (No. 21104078), the Project of Science and Technology of Jilin Province, China (No. 201201096), and the Scientific Research Starting Foundation for the Jilin Agricultural University, China (No. 201212).

摘要: The morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution were systematically studied by tuning the solvent property using self-consistent field simulation. The solvent property was tuned by changing the Flory-Huggins interaction parameters between each type of blocks and solvent, respectively. The simulation results show that by changing the solvent properties, a series of micelle morphologies such as vesicle, cage-like, ring-shaped, rod-like and spherical micelle morphologies can be obtained. Variations of the free energy of the solution system and the surface area of micelles with the Flory-Huggins interaction parameters were calculated to better understand the effect of solvent property on micelle morphologies. In addition, a phase diagram showing the morphological changes of micelles with the Flory-Huggins interaction parameters is provided.

English


    1. [1]

      Ding, J.F. and Liu, G.J., Macromolecules, 1997, 30: 655

    2. [2]

      Discher, B.M., Won, Y.Y., Ege, D.S., Lee, J.C.M., Bates, F.S., Discher, D.E. and Hammer, D.A., Science, 1999, 284: 1143

    3. [3]

      Li, Z.C., Shen, Y., Liang, Y.Z. and Li, F.M., Chinese J. Polym. Sci., 2001, 19(3): 297

    4. [4]

      Zhu, J.T., Liao, Y.G. and Jiang, W., Langmuir, 2004, 20: 3809

    5. [5]

      Massey, J., Power, K.N., Manners, I. and Winnik, M.A., J. Am. Chem. Soc., 1998, 120: 9533

    6. [6]

      Vriezema, D.M., Hoogboom, J., Velonia, K., Takazawa, K., Christianen, P.C.M., Maan, J.C., Rowan, A.E. and Nolte, R.J.M., Angew. Chem. Int. Ed., 2003, 42: 772

    7. [7]

      Chan, Y.N., Lu, X.L., Chen, E.Q. and Mi, Y.L., Polymer, 2004, 45: 3465

    8. [8]

      Jenekhe, S.A. and Chen, X.L., Science, 1998, 279: 1903

    9. [9]

      Beck, J.S., Vartuli, J.C., Roth, W.J., Leonowicz, M.E., Kresge, C.T., Schmitt, K.D., Chu, C.T.W., Olson, D.H., Sheppard, E.W., McCullen, S.B., Higgins, J.B. and Schlenker, J.L., J. Am. Chem. Soc., 1992, 114: 10834

    10. [10]

      Savic, R., Luo, L.B., Eisenberg, A. and Maysinger, D., Science, 2003, 300: 615

    11. [11]

      Allen, C., Maysinger, D. and Eisenberg, A., Colloids Surf. B, 1999, 16: 3

    12. [12]

      Zhang, L.F. and Eisenberg, A., Science, 1995, 268: 1728

    13. [13]

      Zhang, L.F. and Eisenberg, A., Polym. Adv. Tec., 1998, 9: 677

    14. [14]

      Zhang, L F. and Eisenberg, A., J. Am. Chem. Soc., 1996, 118: 3168

    15. [15]

      Matsen, M.W. and Schick, M., Phys. Rev. Lett., 1994, 72: 2660

    16. [16]

      Stoenescu, R. and Meier, M., Chem. Commun., 2002, 3016

    17. [17]

      Yu, G. and Eisenberg, A., Macromolecules, 1998, 31: 5546

    18. [18]

      Wang, R., Tang, P., Qiu, F. and Yang, Y.L., J. Phys. Chem. B, 2005, 109: 17120

    19. [19]

      Xin, X., Xu, G.Y., Zhang, Z.Q., Chen,Y.J. and Wang, F., Eur. Polym. J., 2007, 43: 3106

    20. [20]

      Zhu, Y.T., Li, R.K.Y. and Jiang, W., Chem. Phys., 2006, 327: 137

    21. [21]

      Zhulina, E.B. and Borisov, O.V., Macromolecules, 2008, 41: 5934

    22. [22]

      Cui, J., Li, W. and Jiang, W., Chinese J. Polym. Sci., 2013, 31(9): 1225

    23. [23]

      Zhang, L.S., Lin, J.P. and Lin, S.L., J. Phys. Chem. B, 2007, 111: 9209

    24. [24]

      Ma, J.W., Li, X., Tang, P. and Yang, Y.L., J. Phys. Chem. B, 2007, 111: 1552

    25. [25]

      Zhuang, Y., Lin, J.P., Wang, L.Q. and Zhang, L.S., J. Phys. Chem. B, 2009, 113: 1906

    26. [26]

      Uneyama, T. and Doi, M., Macromolecules, 2005, 38: 5817

    27. [27]

      Qiu, W.J., Li, S.B., Ji, Y.Y. and Zhang, L.X., Chinese J. Polym. Sci., 2013, 31(1): 122

    28. [28]

      Suo, T.C., Yan, D.D., Yang, S. and Shi, A.C., Macromolecules, 2009, 42: 6791

    29. [29]

      Jiang, Y., Zhu, J.T., Jiang, W. and Liang, H.J., J. Phys. Chem. B, 2005, 109: 21549

    30. [30]

      Zhu, J.T., Yu, H.Z. and Jiang, W., Macromolecules, 2005, 38: 7492

    31. [31]

      Zhu, J.T., Jiang, Y., Liang, H.J, and Jiang, W., J. Phys. Chem. B, 2005, 109: 8619

    32. [32]

      Zhu, J.T., and Jiang, W., Macromolecules, 2005, 38: 9315

    33. [33]

      Kong, W.X., Li, B.H., Jin, Q.H, and Ding, D.T., Langmuir, 2010, 26: 4226

    34. [34]

      Fredrickson, G.H., Ganesan, V. and Drolet, F., Macromolecules, 2002, 35: 16

    35. [35]

      Drolet, F. and Fredrickson, G.H., Macromolecules, 2001, 34: 5317

    36. [36]

      Drolet, F. and Fredrickson, G.H., Phys. Rev. Lett., 1999, 83: 4317

    37. [37]

      He, X.H., Liang, H.J., Huang, L. and Pan, C.Y., J. Phys. Chem. B, 2004, 108: 1731

    38. [38]

      Du, H.B., Zhu, J.T. and Jiang, W., J. Phys. Chem. B, 2007, 111: 1938

    39. [39]

      Bhargava, P., Tu, Y.F., Zheng, J.X., Xiong, H.M., Quirk, R.P. and Cheng, S.Z.D., J. Am. Chem. Soc., 2007, 129: 1113

    40. [40]

      Jain, S. and Bate, F.S., Science, 2003, 300: 460

  • 加载中
计量
  • PDF下载量:  0
  • 文章访问数:  2083
  • HTML全文浏览量:  73
文章相关
  • 发布日期:  2014-12-05
  • 收稿日期:  2014-03-31
  • 修回日期:  2014-07-24
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章