Citation: De-liang He, Fei Li, San-bao Xia, Fu-rong Liu, Ying Xiong, Quan Zhang. Synthesis and Characterization of a Novel Ionic Liquid Polymer：Poly(1-(3-aminobenzyl)-3-methylimidazolium chloride)[J]. Chinese Journal of Polymer Science, ;2014, 32(2): 163-168. doi: 10.1007/s10118-014-1385-1 shu

Synthesis and Characterization of a Novel Ionic Liquid Polymer：Poly(1-(3-aminobenzyl)-3-methylimidazolium chloride)

De-liang He ^1,, ,
Fei Li ¹ ,
San-bao Xia ¹ ,
Fu-rong Liu ¹ ,
Ying Xiong ¹ ,
Quan Zhang ²

1.
College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
2.
College of Civil Engineering, Hunan University, Changsha 410082, China

Corresponding author: De-liang He,
Received Date: 28 March 2013
Revised Date: 27 July 2013

Fund Project: This work was financially supported by the Hunan Provincial Natural Science Foundation of China (Nos. 11JJ3015 and 11JJ1009).

A new type of polymerizable ionic liquid (IL) 1-(3-aminobenzyl)-3-methylimidazolium chloride (AMIC) was synthesized to obtain a novel polymer salt poly(1-(3-aminobenzyl)-3-methylimidazolium chloride) (PAMIC). The AMIC was structurally characterized by mass spectrometry and Fourier transform infrared spectrometry (FTIR). The structure, morphology and properties of PAMIC were investigated by FTIR, ultraviolet visible absorption spectra (UV-Vis), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), conductivity measurement and thermo-gravimetric analysis (TGA). The PAMIC was spherulitic with an average diameter of about 50 nm and showed high conductivity and excellent thermal stability.
- Ionic liquid,
- 1-(3-Aminobenzyl)-3-methylimidazolium chloride,
- Polymerization,
- Poly(1-(3-aminobenzyl)-3-methylimidazolium chloride)
1. [1]
1. [1]
  Tong Zhang , Xiaojing Liang , Licheng Wang , Shuai Wang , Xiaoxiao Liu , Yong Guo . An ionic liquid assisted hydrogel functionalized silica stationary phase for mixed-mode liquid chromatography. Chinese Chemical Letters, 2025, 36(1): 109889-. doi: 10.1016/j.cclet.2024.109889
2. [2]
  Xiang Li , Beibei Zhang , Zhixiang Wang , Xiangyu Chen . Organocatalyzed iodine-mediated reversible-deactivation radical polymerization via photoinduced charge transfer complex catalysis. Chinese Chemical Letters, 2025, 36(6): 110383-. doi: 10.1016/j.cclet.2024.110383
3. [3]
  Bingxu Chen , Lei Yi , Ruixi Xie , Rui Gao , Jia Yu , Siqi Shi . Enable high-power fluorinated graphite cathode for lithium primary batteries by metallic ionic liquid-derived surface activation engineering. Chinese Chemical Letters, 2026, 37(6): 111040-. doi: 10.1016/j.cclet.2025.111040
4. [4]
  Wensheng Li , Zhiqiang Sun , Yidi Chen , Xiaoguang Duan , Chuling Guo , Zhi Dang , Shih-Hsin Ho , Shishu Zhu . Fenton-like catalysis of single-atom Co-N₄ for polymeric transformation and recovery of benzohydroxamic acid in mineral processing wastewater. Chinese Chemical Letters, 2026, 37(5): 111791-. doi: 10.1016/j.cclet.2025.111791
5. [5]
  Boyuan Hu , Jian Zhang , Yulin Yang , Yayu Dong , Jiaqi Wang , Wei Wang , Kaifeng Lin , Debin Xia . Dual-functional POM@IL complex modulate hole transport layer properties and interfacial charge dynamics for highly efficient and stable perovskite solar cells. Chinese Chemical Letters, 2024, 35(7): 108933-. doi: 10.1016/j.cclet.2023.108933
6. [6]
  Aonan Wang , Jingwen Dai , Yiming Guo , Fanghua Ning , Xiaoyu Liu , Sidra Subhan , Jiaqian Qin , Shigang Lu , Jin Yi . Imidazolium bromide based dual-functional redox mediator for the construction of dendrite-free Li-CO₂ batteries. Chinese Chemical Letters, 2025, 36(7): 110186-. doi: 10.1016/j.cclet.2024.110186
7. [7]
  Feng Xu , Ziqi Ning , Donghua Zhang , Chunlong Dai , Qinxue Wen , Fengxia Deng , Bo Lai , Zhiqiang Chen . Mechanism and pathway for the electrocatalytic degradation of an organic phosphine scale inhibitor by a novel Ti/IrO₂-RuO₂(Bi+[Emim]BF₄) electrode. Chinese Chemical Letters, 2026, 37(10): 112435-. doi: 10.1016/j.cclet.2026.112435
8. [8]
  Yameen Ahmed , Xiangxiang Feng , Yuanji Gao , Yang Ding , Caoyu Long , Mustafa Haider , Hengyue Li , Zhuan Li , Shicheng Huang , Makhsud I. Saidaminov , Junliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057
9. [9]
  Rong-Nan Yi , Wei-Min He . Photocatalytic Minisci-type multicomponent reaction for the synthesis of 1-(halo)alkyl-3-heteroaryl bicyclo[1.1.1]pentanes. Chinese Chemical Letters, 2024, 35(10): 110115-. doi: 10.1016/j.cclet.2024.110115
10. [10]
  Xiao-Yu Han , Si-Hua Liu , Su-Yun Zhang , Jian-Ke Sun . Functionally graded materials based on porous poly(ionic liquid)s: Design strategies and applications. Chinese Journal of Structural Chemistry, 2025, 44(7): 100601-100601. doi: 10.1016/j.cjsc.2025.100601
11. [11]
  Haiyang Liao , Tiemin Xiao , Tengfei Zhang , Chiam Wen Liew , Xiaofei Duan , Jiayi Su , Hongjin Kuang , Xiaolong Feng , Ting Li , Yongqi Zhang . Zwitterionic poly(ionic liquid)-induced fast structural diffusion electrolytes for lithium metal batteries. Chinese Chemical Letters, 2026, 37(9): 111344-. doi: 10.1016/j.cclet.2025.111344
12. [12]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
13. [13]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
14. [14]
  Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . 高频超声法制备聚多巴胺薄膜综合实验. University Chemistry, 2025, 40(6): 210-214. doi: 10.12461/PKU.DXHX202407081
15. [15]
  Fei Yin , Erli Yang , Xue Ge , Qian Sun , Fan Mo , Guoqiu Wu , Yanfei Shen . Coupling WO₃₋_x dots-encapsulated metal-organic frameworks and template-free branched polymerization for dual signal-amplified electrochemiluminescence biosensing. Chinese Chemical Letters, 2024, 35(4): 108753-. doi: 10.1016/j.cclet.2023.108753
16. [16]
  Yajun Hou , Jinxin Liu , Tao Chen , Yi Zhang , Lei Zhou . Sonogashira coupling reaction in ionic liquids: a detailed exploration of experiment 4.4D in the “101 Plan” synthetic chemistry curriculum. University Chemistry, 2026, 41(6): 136-144. doi: 10.12461/PKU.DXHX202510101
17. [17]
  Hua Yu , Dingdu Chen , Xuan Wang , Lijun Yang , Geming Wang , Pu Hu . MOF-encapsulated phosphorus/nitrogen ionic liquid as a multifunctional flame-retardant additive for high-safety lithium-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(7): 100201-0. doi: 10.1016/j.actphy.2025.100201
18. [18]
  Huijuan Liao , Yulin Xiao , Dong Xue , Mingyu Yang , Jianyang Dong . Synthesis of 1-Benzyl Isoquinoline via the Minisci Reaction. University Chemistry, 2025, 40(7): 294-299. doi: 10.12461/PKU.DXHX202409092
19. [19]
  Haoran Yu , Liang Cao , Jiajia Wang , Jian Guo , Ji Zhang , Shan-Tao Zhang . "Soft" to "hard" transition and balanced performance in Pb(Ni_1/3Nb_2/3)O₃-Pb(Mn_1/3Nb_2/3)O₃-PbZrO₃-PbTiO₃: Sm. Chinese Chemical Letters, 2026, 37(10): 111560-. doi: 10.1016/j.cclet.2025.111560
20. [20]
  Liming Zhang , Chenjie Lou , Shuaika Liang , Wei Xia , Rui Wang , Longfei Li , Chengyu Fu , Mingxue Tang , Rong Xiang , Wei Wang , Yichun Xu , Hongfa Xiang , Xuyong Feng . Boosting ionic conductivity in Li_xAlCl_3-xO_x solid electrolytes through anion-mixing-engineered ion diffusion channels. Chinese Chemical Letters, 2026, 37(10): 111558-. doi: 10.1016/j.cclet.2025.111558

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(2057)
HTML views(62)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return