Citation: Jie Cui, Wei Li, Wei Jiang. SIMULATION STUDY OF CO-ASSEMBLY OF ABC TRIBLOCK COPOLYMER/NANOPARTICLE INTO MULTICOMPARTMENT HYBRIDS IN SELECTIVE SOLVENT[J]. Chinese Journal of Polymer Science, ;2013, 31(9): 1225-1232. doi: 10.1007/s10118-013-1323-7 shu

SIMULATION STUDY OF CO-ASSEMBLY OF ABC TRIBLOCK COPOLYMER/NANOPARTICLE INTO MULTICOMPARTMENT HYBRIDS IN SELECTIVE SOLVENT

Corresponding author: Wei Jiang,
Received Date: 21 March 2013
Revised Date: 17 May 2013

Fund Project: This work was financially supported by the National Natural Science Foundation of China for General Program (No. 21274145).

Co-assembly of ABC linear triblock copolymer/nanoparticle into bump-surface multicompartment hybrids in selective solvent was studied through self-consistent field theory (SCFT) simulation. Results from three-dimensional SCFT simulation showed that the hybrid morphology depended on the length and number of grafted chains, whereas the number and shape of bumps relied on nanoparticle size. Moreover, the simulation results showed that the length and number of grafted chains had equivalent effect on hybrid morphology. Calculated results indicated that entropy was a more important factor than enthalpy in the co-assembly.
- Co-assembly,
- Triblock copolymer,
- Nanoparticle,
- Multicompartment hybrid,
- Self-consistent field theory
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