引用本文:
Xiu Yang LU, Qi JING, Zhun LI, Lei YUAN, Fei GAO, Xin LIU. Enhanced Acid/Base Catalysis in High Temperature Liquid Water[J]. Chinese Chemical Letters,
2006, 17(6): 841-844.
Citation: Xiu Yang LU, Qi JING, Zhun LI, Lei YUAN, Fei GAO, Xin LIU. Enhanced Acid/Base Catalysis in High Temperature Liquid Water[J]. Chinese Chemical Letters, 2006, 17(6): 841-844.
Citation: Xiu Yang LU, Qi JING, Zhun LI, Lei YUAN, Fei GAO, Xin LIU. Enhanced Acid/Base Catalysis in High Temperature Liquid Water[J]. Chinese Chemical Letters, 2006, 17(6): 841-844.
Enhanced Acid/Base Catalysis in High Temperature Liquid Water
摘要:
Two novel and environmentally benign solvent systems, organic acids-enriched high temperature liquid water (HTLW) and NH3-enriched HTLW, were developed, which can enhance the reaction rate of acid/base-catalyzed organic reactions in HTLW. We investigated the decomposition of fructose in organic acids-enriched HTLW, hydrolysis of cinnamaldehyde and aldol condensation of phenylaldehyde with acetaldehyde in NH3-enriched HTLW. The experimental results demonstrated that organic acids-enriched or NH3-enriched HTLW can greatly accelerate acid/base-catalyzed organic reactions in HTLW.
English
Enhanced Acid/Base Catalysis in High Temperature Liquid Water
Abstract:
Two novel and environmentally benign solvent systems, organic acids-enriched high temperature liquid water (HTLW) and NH3-enriched HTLW, were developed, which can enhance the reaction rate of acid/base-catalyzed organic reactions in HTLW. We investigated the decomposition of fructose in organic acids-enriched HTLW, hydrolysis of cinnamaldehyde and aldol condensation of phenylaldehyde with acetaldehyde in NH3-enriched HTLW. The experimental results demonstrated that organic acids-enriched or NH3-enriched HTLW can greatly accelerate acid/base-catalyzed organic reactions in HTLW.
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Key words:
- High temperature liquid water
- / acid/base-catalysis
- / organic reactions
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