Synthesis of Novel C2-Symmetrical Bidentate Phosphoramidite Ligands for Rh-catalyzed Asymmetric Hydrogenation of β-(Acylamino)acrylates

Qing Heng ZENG Xiang Ping HU Xin Miao LIANG Zhuo ZHENG

引用本文: Qing Heng ZENG,  Xiang Ping HU,  Xin Miao LIANG,  Zhuo ZHENG. Synthesis of Novel C2-Symmetrical Bidentate Phosphoramidite Ligands for Rh-catalyzed Asymmetric Hydrogenation of β-(Acylamino)acrylates[J]. Chinese Chemical Letters, 2006, 17(6): 711-713. shu
Citation:  Qing Heng ZENG,  Xiang Ping HU,  Xin Miao LIANG,  Zhuo ZHENG. Synthesis of Novel C2-Symmetrical Bidentate Phosphoramidite Ligands for Rh-catalyzed Asymmetric Hydrogenation of β-(Acylamino)acrylates[J]. Chinese Chemical Letters, 2006, 17(6): 711-713. shu

Synthesis of Novel C2-Symmetrical Bidentate Phosphoramidite Ligands for Rh-catalyzed Asymmetric Hydrogenation of β-(Acylamino)acrylates

  • 基金项目:

    The authors would like to thank the National Natural Science Foundation of China (No. 20472083) for financial support of this work.

摘要: Two new C2-symmetrical bidentate phosphoramidite ligands were synthesized and employed in the Rh-catalyzed asymmetric hydrogenation of β-(acylamino)acrylates, up to 89% ee with full conversions was obtained.

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  • 收稿日期:  2005-10-25
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