引用本文:
Xu Dong LIU, Xiao Li BAI, Xue Peng QIU, Lian Xun GAO. Asymmetric Phase-transfer Mediated Epoxidation of α,β-Enones Using Dendritic Catalysts Derived from Cinchona Alkaloids[J]. Chinese Chemical Letters,
2005, 16(7): 975-978.
Citation: Xu Dong LIU, Xiao Li BAI, Xue Peng QIU, Lian Xun GAO. Asymmetric Phase-transfer Mediated Epoxidation of α,β-Enones Using Dendritic Catalysts Derived from Cinchona Alkaloids[J]. Chinese Chemical Letters, 2005, 16(7): 975-978.
Citation: Xu Dong LIU, Xiao Li BAI, Xue Peng QIU, Lian Xun GAO. Asymmetric Phase-transfer Mediated Epoxidation of α,β-Enones Using Dendritic Catalysts Derived from Cinchona Alkaloids[J]. Chinese Chemical Letters, 2005, 16(7): 975-978.
Asymmetric Phase-transfer Mediated Epoxidation of α,β-Enones Using Dendritic Catalysts Derived from Cinchona Alkaloids
摘要:
Chiral phase-transfer catalysts, derived from cinchona alkaloids and Frechet dendritic wedges up to generation two, have been synthesized. These chiral dendritic molecules have been used as PTCs in the epoxidation of α,β-enones, showing a moderate level of asymmetric induction.
English
Asymmetric Phase-transfer Mediated Epoxidation of α,β-Enones Using Dendritic Catalysts Derived from Cinchona Alkaloids
Abstract:
Chiral phase-transfer catalysts, derived from cinchona alkaloids and Frechet dendritic wedges up to generation two, have been synthesized. These chiral dendritic molecules have been used as PTCs in the epoxidation of α,β-enones, showing a moderate level of asymmetric induction.
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Key words:
- Asymmetric epoxidation
- / phase-transfer catalysis
- / cinchona alkaloids
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