引用本文:
Hui Mou LUO, Yi Qun LI, Wen Jie ZHENG. A Novel Ionic Liquid/water Biphasic System for the Preparation of Oximes[J]. Chinese Chemical Letters,
2005, 16(7): 906-908.
Citation: Hui Mou LUO, Yi Qun LI, Wen Jie ZHENG. A Novel Ionic Liquid/water Biphasic System for the Preparation of Oximes[J]. Chinese Chemical Letters, 2005, 16(7): 906-908.
Citation: Hui Mou LUO, Yi Qun LI, Wen Jie ZHENG. A Novel Ionic Liquid/water Biphasic System for the Preparation of Oximes[J]. Chinese Chemical Letters, 2005, 16(7): 906-908.
A Novel Ionic Liquid/water Biphasic System for the Preparation of Oximes
摘要:
A variety of carbonyl compounds can be converted into oximes efficiently and conveniently in a novel ionic liquid/water bi-phasic system in the presence of sodium bicarbonate at ambient temperature. The ionic liquid 1-butyl-3-methyl imidazolium hexafluorophosphate[bmim]PF6 is immiscible with water or diethyl ether and can be easily recycled for reuse without noticeable droping in activity after separation of the products. The protocol is rapid, the yields are excellent, the method is simple and the ionic liquid can be reused.
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关键词:
- Oximes
- / synthesis
- / ionic liquid
- / bi-phasic system
English
A Novel Ionic Liquid/water Biphasic System for the Preparation of Oximes
Abstract:
A variety of carbonyl compounds can be converted into oximes efficiently and conveniently in a novel ionic liquid/water bi-phasic system in the presence of sodium bicarbonate at ambient temperature. The ionic liquid 1-butyl-3-methyl imidazolium hexafluorophosphate[bmim]PF6 is immiscible with water or diethyl ether and can be easily recycled for reuse without noticeable droping in activity after separation of the products. The protocol is rapid, the yields are excellent, the method is simple and the ionic liquid can be reused.
-
Key words:
- Oximes
- / synthesis
- / ionic liquid
- / bi-phasic system
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