引用本文:
Yan XU, Hai Xian WANG, Yong FU, Mao Ping SONG, Yang Jie WU. Synthesis and Crystal Structure of a Novel Hetero-six-nuclear Copper-iron Cluster Containing Ferroceylphenyl Groups[J]. Chinese Chemical Letters,
2005, 16(7): 883-885.
Citation: Yan XU, Hai Xian WANG, Yong FU, Mao Ping SONG, Yang Jie WU. Synthesis and Crystal Structure of a Novel Hetero-six-nuclear Copper-iron Cluster Containing Ferroceylphenyl Groups[J]. Chinese Chemical Letters, 2005, 16(7): 883-885.
Citation: Yan XU, Hai Xian WANG, Yong FU, Mao Ping SONG, Yang Jie WU. Synthesis and Crystal Structure of a Novel Hetero-six-nuclear Copper-iron Cluster Containing Ferroceylphenyl Groups[J]. Chinese Chemical Letters, 2005, 16(7): 883-885.
Synthesis and Crystal Structure of a Novel Hetero-six-nuclear Copper-iron Cluster Containing Ferroceylphenyl Groups
摘要:
A new hetero-six-nuclear cluster was synthesized and determined by X-ray diffraction technique. The four-carboxylate groups are bound to the Cu(Ⅱ) atoms to form Cu(OR)4Cu paddle-wheel-type cage between two DMF as the basis for the cluster. The distance of two copper(Ⅱ) atoms is 2.642 Å, and they are bridged by the carboxylate groups. A huge system plane was auto-assembled by four host molecules and two Cu (Ⅱ) ions, which was observed in the crystal structure.
English
Synthesis and Crystal Structure of a Novel Hetero-six-nuclear Copper-iron Cluster Containing Ferroceylphenyl Groups
Abstract:
A new hetero-six-nuclear cluster was synthesized and determined by X-ray diffraction technique. The four-carboxylate groups are bound to the Cu(Ⅱ) atoms to form Cu(OR)4Cu paddle-wheel-type cage between two DMF as the basis for the cluster. The distance of two copper(Ⅱ) atoms is 2.642 Å, and they are bridged by the carboxylate groups. A huge system plane was auto-assembled by four host molecules and two Cu (Ⅱ) ions, which was observed in the crystal structure.
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Key words:
- Ferrocene
- / hetero-six-nuclear cluster
- / copper
- / crystal structure
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