Photosensitization of trans-Vitamin D3 to cis-Vitamin D3 in Heterogeneous System

Yong Bin HAN Jin Ping CHEN Yun Yan GAO Bai Ning LIU Guo Qiang YANG Yi LI

引用本文: Yong Bin HAN,  Jin Ping CHEN,  Yun Yan GAO,  Bai Ning LIU,  Guo Qiang YANG,  Yi LI. Photosensitization of trans-Vitamin D3 to cis-Vitamin D3 in Heterogeneous System[J]. Chinese Chemical Letters, 2005, 16(7): 871-874. shu
Citation:  Yong Bin HAN,  Jin Ping CHEN,  Yun Yan GAO,  Bai Ning LIU,  Guo Qiang YANG,  Yi LI. Photosensitization of trans-Vitamin D3 to cis-Vitamin D3 in Heterogeneous System[J]. Chinese Chemical Letters, 2005, 16(7): 871-874. shu

Photosensitization of trans-Vitamin D3 to cis-Vitamin D3 in Heterogeneous System

  • 基金项目:

    This work was supported by the Major State Basic Research Development Program, Grant No. G2000078100, the National Natural Science Foundation of China, No. 20172059 and Chinese Academy of Sciences.

摘要: Two modes of heterogeneous photoisomerization of trans-vitamin D3 to cis-vitamin D3are described. The occurrence of isomerization on the substrate bounded to the polymeric support gives us the possibility in succession synthesis of 1α-hydroxyvitamin D3. The polymer-bound anthracene can sensitize isomerization of trans-vitamin D3 to cis-vitamin D3 efficiently and ease the separation process.

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  • 收稿日期:  2004-07-19
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