引用本文:
Li Jing FANG, Chen Xi ZHANG, Jin Chun CHEN, Guo Jun ZHENG, Yu Lin LI. Total Synthesis of Two 4, 5-Dioxo-seco-eudesmane Sesquiterpenes[J]. Chinese Chemical Letters,
2005, 16(5): 569-571.
Citation: Li Jing FANG, Chen Xi ZHANG, Jin Chun CHEN, Guo Jun ZHENG, Yu Lin LI. Total Synthesis of Two 4, 5-Dioxo-seco-eudesmane Sesquiterpenes[J]. Chinese Chemical Letters, 2005, 16(5): 569-571.
Citation: Li Jing FANG, Chen Xi ZHANG, Jin Chun CHEN, Guo Jun ZHENG, Yu Lin LI. Total Synthesis of Two 4, 5-Dioxo-seco-eudesmane Sesquiterpenes[J]. Chinese Chemical Letters, 2005, 16(5): 569-571.
Total Synthesis of Two 4, 5-Dioxo-seco-eudesmane Sesquiterpenes
摘要:
A facile synthetic route to two seco-eudesmane, 4, 5-dioxo-10-epi-4, 5-seco-γeudesmane (1) and 4, 5-dioxo-10-epi-4, 5-seco-γ-eudesmol (2) from (+)-dihydrocarvone has been described. Avoiding expensive reagents, this highly economic method especially suits for the synthesis of 4, 5-seco-eudesman-type and ophianon-type sesquiterpenes with a double bond at position 11 and 12.
English
Total Synthesis of Two 4, 5-Dioxo-seco-eudesmane Sesquiterpenes
Abstract:
A facile synthetic route to two seco-eudesmane, 4, 5-dioxo-10-epi-4, 5-seco-γeudesmane (1) and 4, 5-dioxo-10-epi-4, 5-seco-γ-eudesmol (2) from (+)-dihydrocarvone has been described. Avoiding expensive reagents, this highly economic method especially suits for the synthesis of 4, 5-seco-eudesman-type and ophianon-type sesquiterpenes with a double bond at position 11 and 12.
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Key words:
- Dihydrocarvone
- / 4,5-dioxo-seco-eudesmane
- / sesquiterpenes
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