引用本文:
Xiao Qi ZHENG, Yong Hui WANG, Qing Xiang GUO, Li YANG, You Cheng LIU. A Large Conformational Change of a Bridged β-Cyclodextrin Dimer in Aqueous Solution[J]. Chinese Chemical Letters,
2003, 14(8): 848-851.
Citation: Xiao Qi ZHENG, Yong Hui WANG, Qing Xiang GUO, Li YANG, You Cheng LIU. A Large Conformational Change of a Bridged β-Cyclodextrin Dimer in Aqueous Solution[J]. Chinese Chemical Letters, 2003, 14(8): 848-851.
Citation: Xiao Qi ZHENG, Yong Hui WANG, Qing Xiang GUO, Li YANG, You Cheng LIU. A Large Conformational Change of a Bridged β-Cyclodextrin Dimer in Aqueous Solution[J]. Chinese Chemical Letters, 2003, 14(8): 848-851.
A Large Conformational Change of a Bridged β-Cyclodextrin Dimer in Aqueous Solution
摘要:
A novel bridged β-CD dimer in which two β-cyclodextrins were linked by a naphthalene at positions 2 and 7 has been synthesized.1H and 13CNMR measurements showed that a large change in the conformation of the dimer occurred in aqueous solution. The dimer interacted with methyl and ethyl orange to form stable inclusion complexes via "induced fit" mechanism.
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关键词:
- Cyclodextrin dimer
- / ethyl orange
- / enzyme mimic
- / induced fit
English
A Large Conformational Change of a Bridged β-Cyclodextrin Dimer in Aqueous Solution
Abstract:
A novel bridged β-CD dimer in which two β-cyclodextrins were linked by a naphthalene at positions 2 and 7 has been synthesized.1H and 13CNMR measurements showed that a large change in the conformation of the dimer occurred in aqueous solution. The dimer interacted with methyl and ethyl orange to form stable inclusion complexes via "induced fit" mechanism.
-
Key words:
- Cyclodextrin dimer
- / ethyl orange
- / enzyme mimic
- / induced fit
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