引用本文:
Wei Ming XU, You Chu ZHANG, Xian HUANG. Polystyrene-supported Selenides and Selenoxide:Versatile Routes to Synthesize Allylic Alcohols[J]. Chinese Chemical Letters,
2003, 14(8): 797-799.
Citation: Wei Ming XU, You Chu ZHANG, Xian HUANG. Polystyrene-supported Selenides and Selenoxide:Versatile Routes to Synthesize Allylic Alcohols[J]. Chinese Chemical Letters, 2003, 14(8): 797-799.
Citation: Wei Ming XU, You Chu ZHANG, Xian HUANG. Polystyrene-supported Selenides and Selenoxide:Versatile Routes to Synthesize Allylic Alcohols[J]. Chinese Chemical Letters, 2003, 14(8): 797-799.
Polystyrene-supported Selenides and Selenoxide:Versatile Routes to Synthesize Allylic Alcohols
摘要:
Several polystyrene-supported selenides and selenoxide have been prepared firstly. These novel reagents were treated with LDA to produce selenium stabilized carbanions, which reacted with aldehydes and alkyl halides, followed by selenoxide syn-elimination and [2,3] sigmatropic rearrangement respectively to give Z-allylic alcohols stereoselectively.
English
Polystyrene-supported Selenides and Selenoxide:Versatile Routes to Synthesize Allylic Alcohols
Abstract:
Several polystyrene-supported selenides and selenoxide have been prepared firstly. These novel reagents were treated with LDA to produce selenium stabilized carbanions, which reacted with aldehydes and alkyl halides, followed by selenoxide syn-elimination and [2,3] sigmatropic rearrangement respectively to give Z-allylic alcohols stereoselectively.
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Key words:
- Solid phase synthesis
- / selenides and selenoxide
- / allylic alcohol
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