引用本文:
Chun Bao LI, Peng Wu ZHENG, Zhu Xuan ZHAO, Wen Qin ZHANG, Meng Bao LI, Qi Chao YANG, Yi CUI, Yan Li XU. Reduction of Azides to Amines with New Metal/Lewis Acid Systems in H2O or Aqueous EtOH[J]. Chinese Chemical Letters,
2003, 14(8): 773-775.
Citation: Chun Bao LI, Peng Wu ZHENG, Zhu Xuan ZHAO, Wen Qin ZHANG, Meng Bao LI, Qi Chao YANG, Yi CUI, Yan Li XU. Reduction of Azides to Amines with New Metal/Lewis Acid Systems in H2O or Aqueous EtOH[J]. Chinese Chemical Letters, 2003, 14(8): 773-775.
Citation: Chun Bao LI, Peng Wu ZHENG, Zhu Xuan ZHAO, Wen Qin ZHANG, Meng Bao LI, Qi Chao YANG, Yi CUI, Yan Li XU. Reduction of Azides to Amines with New Metal/Lewis Acid Systems in H2O or Aqueous EtOH[J]. Chinese Chemical Letters, 2003, 14(8): 773-775.
Reduction of Azides to Amines with New Metal/Lewis Acid Systems in H2O or Aqueous EtOH
摘要:
The azides were reduced to the corresponding amines by two new metal/Lewis acid systems in water or in aqueous EtOH in yields ranging from 80%-95%. The reaction rates were faster in water than in aqueous EtOH in most cases. All 16 azides with different functional groups were well reduced to the corresponding amines in excellent yields and reaction rates.
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关键词:
- Azides
- / reduction
- / metals
- / Lewis acids
English
Reduction of Azides to Amines with New Metal/Lewis Acid Systems in H2O or Aqueous EtOH
Abstract:
The azides were reduced to the corresponding amines by two new metal/Lewis acid systems in water or in aqueous EtOH in yields ranging from 80%-95%. The reaction rates were faster in water than in aqueous EtOH in most cases. All 16 azides with different functional groups were well reduced to the corresponding amines in excellent yields and reaction rates.
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Key words:
- Azides
- / reduction
- / metals
- / Lewis acids
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