引用本文:
Xiang Ping HU, Hui Lin CHEN, Hui Cong DAI, Xin Quan HU, Zhuo ZHENG. Synthesis and Potential Application of Novel C2-Symmetrical Bis(ferrocenyl) P2N Ligand[J]. Chinese Chemical Letters,
2003, 14(11): 1113-1115.
Citation: Xiang Ping HU, Hui Lin CHEN, Hui Cong DAI, Xin Quan HU, Zhuo ZHENG. Synthesis and Potential Application of Novel C2-Symmetrical Bis(ferrocenyl) P2N Ligand[J]. Chinese Chemical Letters, 2003, 14(11): 1113-1115.
Citation: Xiang Ping HU, Hui Lin CHEN, Hui Cong DAI, Xin Quan HU, Zhuo ZHENG. Synthesis and Potential Application of Novel C2-Symmetrical Bis(ferrocenyl) P2N Ligand[J]. Chinese Chemical Letters, 2003, 14(11): 1113-1115.
Synthesis and Potential Application of Novel C2-Symmetrical Bis(ferrocenyl) P2N Ligand
摘要:
A novel chiral bis(ferrocenyl) P2N ligand 1 with C2-symmetry was synthesized through a four-step procedure from (R)-N,N-dimethyl-1-ferrocenylethylamine. In a model reaction of Pd-catalyzed allylic alkylation of 1,3-diphenylprop-2-enyl acetate 6 with dimethyl malonate, good enantioselectivity (86% e.e.) was obtained.
English
Synthesis and Potential Application of Novel C2-Symmetrical Bis(ferrocenyl) P2N Ligand
Abstract:
A novel chiral bis(ferrocenyl) P2N ligand 1 with C2-symmetry was synthesized through a four-step procedure from (R)-N,N-dimethyl-1-ferrocenylethylamine. In a model reaction of Pd-catalyzed allylic alkylation of 1,3-diphenylprop-2-enyl acetate 6 with dimethyl malonate, good enantioselectivity (86% e.e.) was obtained.
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Key words:
- Synthesis
- / C2-symmetry
- / bis(ferrocenyl) P2N ligand
- / Pd-catalyzed allylic alkylation
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