Direct Observation of Various Al Sites in SAPO-34 by 27Al Multiquantum (MQ) Magic Angle Spinning (MAS) NMR

Zhi Min YAN Jian Qin ZHUANG Lei XU Xiu Wen HAN Zhong Min LIU Xin He BAO

引用本文: Zhi Min YAN,  Jian Qin ZHUANG,  Lei XU,  Xiu Wen HAN,  Zhong Min LIU,  Xin He BAO. Direct Observation of Various Al Sites in SAPO-34 by 27Al Multiquantum (MQ) Magic Angle Spinning (MAS) NMR[J]. Chinese Chemical Letters, 2003, 14(1): 87-90. shu
Citation:  Zhi Min YAN,  Jian Qin ZHUANG,  Lei XU,  Xiu Wen HAN,  Zhong Min LIU,  Xin He BAO. Direct Observation of Various Al Sites in SAPO-34 by 27Al Multiquantum (MQ) Magic Angle Spinning (MAS) NMR[J]. Chinese Chemical Letters, 2003, 14(1): 87-90. shu

Direct Observation of Various Al Sites in SAPO-34 by 27Al Multiquantum (MQ) Magic Angle Spinning (MAS) NMR

  • 基金项目:

    We are gralcful to the support of the National Natural Science Foundation of China and The Ministry of Science and Technology of China

    We appreciate Dr. R. Fu (NHMFL, Tallahassee) for his kind liclp regarding the MQ MAS NMR experiments.

摘要: The elegant 2D multiquantum (MQ) MAS NMR has been applied to invcstigatc the coordination of Al atoms in SAPO-34. The results show that the effects of the template and/or water on the coordination of Al atoms are significanl, which lead to the formation of various Al species. Up to four kinds of Al species are distinctly resolved.

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  • 收稿日期:  2002-03-25
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