引用本文:
Dong Ping ZHAN, Bing Liang WU. A Novel Micro-hole Electrode Used to Investigate Electron Transfer Reactions at ITIES[J]. Chinese Chemical Letters,
2002, 13(3): 273-276.
Citation: Dong Ping ZHAN, Bing Liang WU. A Novel Micro-hole Electrode Used to Investigate Electron Transfer Reactions at ITIES[J]. Chinese Chemical Letters, 2002, 13(3): 273-276.
Citation: Dong Ping ZHAN, Bing Liang WU. A Novel Micro-hole Electrode Used to Investigate Electron Transfer Reactions at ITIES[J]. Chinese Chemical Letters, 2002, 13(3): 273-276.
A Novel Micro-hole Electrode Used to Investigate Electron Transfer Reactions at ITIES
摘要:
A novel micro-hole electrode was fabricated to investigate the electron transfer reaction at the interface between two immiscible electrolyte solutions (ITIES). The electron transfer reaction between ferro/ferricyanide in aqueous phase (W) and ferrocene in 1, 2-dichloroethane (O) phase was studied as a test experiment. The results showed that the diffusion coefficient obtained from the micro-hole electrode was consistent with that obtained at macro-interface. Due to its simplicity and the very small IR drop it will be a useful tool for the study of ITIES systems.
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关键词:
- Micro-hole electrode
- / electron transfer
- / ITIES
English
A Novel Micro-hole Electrode Used to Investigate Electron Transfer Reactions at ITIES
Abstract:
A novel micro-hole electrode was fabricated to investigate the electron transfer reaction at the interface between two immiscible electrolyte solutions (ITIES). The electron transfer reaction between ferro/ferricyanide in aqueous phase (W) and ferrocene in 1, 2-dichloroethane (O) phase was studied as a test experiment. The results showed that the diffusion coefficient obtained from the micro-hole electrode was consistent with that obtained at macro-interface. Due to its simplicity and the very small IR drop it will be a useful tool for the study of ITIES systems.
-
Key words:
- Micro-hole electrode
- / electron transfer
- / ITIES
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