Ultrathin Multilayer Films Incorporating Keggin-type Heteropolyanion Clusters

Lin XU ,  En Bo WANG ,  Zhuang LI ,  Hong Yu ZHANG ,  Chao QIN

引用本文: Lin XU,  En Bo WANG,  Zhuang LI,  Hong Yu ZHANG,  Chao QIN. Ultrathin Multilayer Films Incorporating Keggin-type Heteropolyanion Clusters[J]. Chinese Chemical Letters, 2001, 12(12): 1127-1130. shu
Citation:  Lin XU,  En Bo WANG,  Zhuang LI,  Hong Yu ZHANG,  Chao QIN. Ultrathin Multilayer Films Incorporating Keggin-type Heteropolyanion Clusters[J]. Chinese Chemical Letters, 2001, 12(12): 1127-1130. shu

Ultrathin Multilayer Films Incorporating Keggin-type Heteropolyanion Clusters

  • 基金项目:

    This project was financially supported by the National Natural Science Foundation of China (Grant No.29971006).

摘要: Two new ultrathin multiplayer films have been successfully prepared from Keggin-type heteropoly acids H4[SiW12O40] and H3[PMo12040] with polyelectrolytes PEI, PSS, and PAH, using the electrostatic layer-by-layer self-assembly technique. The XR results reveal their film thickness at nanoscale (~20 nm). According to the AFM images, it is believed that the surface roughness (rough degree of film surface) of the polyelectrolyte-polyoxometalate film greatly depends on the kind of polyoxometalates.

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  • 收稿日期:  2001-04-02
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