Simultaneous Reduction of Nitro Group and S-S Bond in Nitrodisulfides by Samarium Diiodide:A New Approach to Benzothiazolines

Xiao Yuan CHEN Wei Hui ZHONG Yong Min ZHANG

引用本文: Xiao Yuan CHEN,  Wei Hui ZHONG,  Yong Min ZHANG. Simultaneous Reduction of Nitro Group and S-S Bond in Nitrodisulfides by Samarium Diiodide:A New Approach to Benzothiazolines[J]. Chinese Chemical Letters, 2000, 11(5): 387-388. shu
Citation:  Xiao Yuan CHEN,  Wei Hui ZHONG,  Yong Min ZHANG. Simultaneous Reduction of Nitro Group and S-S Bond in Nitrodisulfides by Samarium Diiodide:A New Approach to Benzothiazolines[J]. Chinese Chemical Letters, 2000, 11(5): 387-388. shu

Simultaneous Reduction of Nitro Group and S-S Bond in Nitrodisulfides by Samarium Diiodide:A New Approach to Benzothiazolines

  • 基金项目:

    We thank the National Natural Science Foundation Laboratory of China (Project No.29872010) and the Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistr, Chinese Academy of Sciences for financial support.

摘要: Nitrodisulfides were reduced by SmI2/HMPA in anhydrous THF at room temperature to produce active intermediates (samarium thiolates and amides), which were "living" double-anions and reacted smoothly with aldehydes or ketones to afford benzothiazolines in good yields under mild and neutral conditions.

English

  • 加载中
计量
  • PDF下载量:  0
  • 文章访问数:  0
  • HTML全文浏览量:  0
文章相关
  • 收稿日期:  2000-01-21
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章