引用本文:
Wu Yan ZHANG, Ji Yu GUO, Xiao Tian LIANG. Studies on Agarofurans Ⅲ. The Synthesis of 3-Substituted Agarofurans[J]. Chinese Chemical Letters,
2000, 11(4): 301-304.
Citation: Wu Yan ZHANG, Ji Yu GUO, Xiao Tian LIANG. Studies on Agarofurans Ⅲ. The Synthesis of 3-Substituted Agarofurans[J]. Chinese Chemical Letters, 2000, 11(4): 301-304.
Citation: Wu Yan ZHANG, Ji Yu GUO, Xiao Tian LIANG. Studies on Agarofurans Ⅲ. The Synthesis of 3-Substituted Agarofurans[J]. Chinese Chemical Letters, 2000, 11(4): 301-304.
Studies on Agarofurans Ⅲ. The Synthesis of 3-Substituted Agarofurans
摘要:
14-Nor-3-oxodihydroagarofuran (2) was prepared in high yield. From 2, derivatives 12 and 13 were synthesized by Grignard addition. In order to identify the configuration of C-3 in compound 12 and 13, the sterospecific synthesis of compound 12 has been carried out in 5 steps from octalone (14).
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关键词:
- Agarofuran
- / synthesis
English
Studies on Agarofurans Ⅲ. The Synthesis of 3-Substituted Agarofurans
Abstract:
14-Nor-3-oxodihydroagarofuran (2) was prepared in high yield. From 2, derivatives 12 and 13 were synthesized by Grignard addition. In order to identify the configuration of C-3 in compound 12 and 13, the sterospecific synthesis of compound 12 has been carried out in 5 steps from octalone (14).
-
Key words:
- Agarofuran
- / synthesis
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