引用本文:
Zao Ying LI, Cong LI, Xu Ye WU. Synthesis of Polymer-Bonded Quaternary Ammonium Type Metal Porphyrins[J]. Chinese Chemical Letters,
2000, 11(1): 27-28.
Citation: Zao Ying LI, Cong LI, Xu Ye WU. Synthesis of Polymer-Bonded Quaternary Ammonium Type Metal Porphyrins[J]. Chinese Chemical Letters, 2000, 11(1): 27-28.
Citation: Zao Ying LI, Cong LI, Xu Ye WU. Synthesis of Polymer-Bonded Quaternary Ammonium Type Metal Porphyrins[J]. Chinese Chemical Letters, 2000, 11(1): 27-28.
Synthesis of Polymer-Bonded Quaternary Ammonium Type Metal Porphyrins
摘要:
The reaction of pyrrole with 4-hydroxybenzaldehyde and 4-pyridinecarboxaldehyde afforded new porphyrin ligand 1. Treatment of 1 with copper(Ⅱ) acetate, cobalt (Ⅱ) acetate gave complexes 2-3 respectively. 2 and 3 reacted with Merrifield's peptide resin produced 4 and 5. Complexes 4 and 5 reacted with methyl iodide respectively gave 6-7. The new compounds 1-7 have been identified by 1H NMR, IR, MS and UV-visible spectra, elemental analysis and AES.
English
Synthesis of Polymer-Bonded Quaternary Ammonium Type Metal Porphyrins
Abstract:
The reaction of pyrrole with 4-hydroxybenzaldehyde and 4-pyridinecarboxaldehyde afforded new porphyrin ligand 1. Treatment of 1 with copper(Ⅱ) acetate, cobalt (Ⅱ) acetate gave complexes 2-3 respectively. 2 and 3 reacted with Merrifield's peptide resin produced 4 and 5. Complexes 4 and 5 reacted with methyl iodide respectively gave 6-7. The new compounds 1-7 have been identified by 1H NMR, IR, MS and UV-visible spectra, elemental analysis and AES.
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Key words:
- polymer-bonded
- / quaternary ammonium type metal porphyrin
- / synthesis
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