Efficient Isomerization for Preparing thans-2,2-Dimethyl-3-(2,2-dichloroethenyl) cyclopropanecarbonyl Chloride

Jun An MA Run Qiu HUANG Jun Ran CHENG Rui Lian SHAO Zai Guo LI

引用本文: Jun An MA,  Run Qiu HUANG,  Jun Ran CHENG,  Rui Lian SHAO,  Zai Guo LI. Efficient Isomerization for Preparing thans-2,2-Dimethyl-3-(2,2-dichloroethenyl) cyclopropanecarbonyl Chloride[J]. Chinese Chemical Letters, 1999, 10(2): 101-102. shu
Citation:  Jun An MA,  Run Qiu HUANG,  Jun Ran CHENG,  Rui Lian SHAO,  Zai Guo LI. Efficient Isomerization for Preparing thans-2,2-Dimethyl-3-(2,2-dichloroethenyl) cyclopropanecarbonyl Chloride[J]. Chinese Chemical Letters, 1999, 10(2): 101-102. shu

Efficient Isomerization for Preparing thans-2,2-Dimethyl-3-(2,2-dichloroethenyl) cyclopropanecarbonyl Chloride

  • 基金项目:

    We would like to acknowledge the National Natural Science Foundation of' China for financial support. We would also like to thank Professor Guang Ren Li for many helpful discussions and Dr. Jia Zhou for encouragement and advice.

摘要: Traps-2,2-dimethyl-3一(2,2-dichloroethenyl) cyclopropanecarbonyl chloride, which is an important intermediate for insecticides, is obtained by isomerization of the cis/traps-mixture with 4- (N,N-dimethylamino) pyridine (DMAP) in the presence or absence of halogen compounds in good yield.

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  • 收稿日期:  1998-09-04
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