引用本文:
Chao Guo YAN. Reaction of [(μ-RE)(μ-CO)Fe2(CO)6]-[Et3NH]+ (E=S, Se, Te) Salts with Benzenesulfinyl Chloride and Carbon Disulfide[J]. Chinese Chemical Letters,
1999, 10(11): 973-974.
Citation: Chao Guo YAN. Reaction of [(μ-RE)(μ-CO)Fe2(CO)6]-[Et3NH]+ (E=S, Se, Te) Salts with Benzenesulfinyl Chloride and Carbon Disulfide[J]. Chinese Chemical Letters, 1999, 10(11): 973-974.
Citation: Chao Guo YAN. Reaction of [(μ-RE)(μ-CO)Fe2(CO)6]-[Et3NH]+ (E=S, Se, Te) Salts with Benzenesulfinyl Chloride and Carbon Disulfide[J]. Chinese Chemical Letters, 1999, 10(11): 973-974.
Reaction of [(μ-RE)(μ-CO)Fe2(CO)6]-[Et3NH]+ (E=S, Se, Te) Salts with Benzenesulfinyl Chloride and Carbon Disulfide
摘要:
The salts of[(μ-RE)(μ-CO)Fe2(CO)6]-[Et3NH]+(E=S, Se, Te) react with bcnrenesulfinyl chloride to dive the μ-sulfinvl croup brideed complexes(μ-RE)(μ-PnS=O)Fe2(CO)6 in goon yeias.Wnereas the sans [(μ-RS)(μ-CO)Fe2(CO)6)-[Et3NH]+(R=t-Bu, Ph) react with carbon disulfide to yield the dithioformato-brideed anionic salts [(μ-RS)(μ-S=C-S)Fe2(CO)6)-[Et3NH]+, wmcn react in situ at tne exo-suuur atom of the ditmorormato-group with diverse α，β-unsaturated carbonyl compounds to give Michael addition products in moderate yields.
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关键词:
- Cluster
- / carbonyl iron
- / sulfur
- / selenium
- / synthesis
English
Reaction of [(μ-RE)(μ-CO)Fe2(CO)6]-[Et3NH]+ (E=S, Se, Te) Salts with Benzenesulfinyl Chloride and Carbon Disulfide
Abstract:
The salts of[(μ-RE)(μ-CO)Fe2(CO)6]-[Et3NH]+(E=S, Se, Te) react with bcnrenesulfinyl chloride to dive the μ-sulfinvl croup brideed complexes(μ-RE)(μ-PnS=O)Fe2(CO)6 in goon yeias.Wnereas the sans [(μ-RS)(μ-CO)Fe2(CO)6)-[Et3NH]+(R=t-Bu, Ph) react with carbon disulfide to yield the dithioformato-brideed anionic salts [(μ-RS)(μ-S=C-S)Fe2(CO)6)-[Et3NH]+, wmcn react in situ at tne exo-suuur atom of the ditmorormato-group with diverse α，β-unsaturated carbonyl compounds to give Michael addition products in moderate yields.
-
Key words:
- Cluster
- / carbonyl iron
- / sulfur
- / selenium
- / synthesis
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