Reductive Cleavage of S-S Bond by Sm/NiCl2 or Sm/NiCl2·6H2O System:A New Method for the Preparation of Thiolesters

Hua Yue WU Red Er CHEN Yong Min ZHANG

引用本文: Hua Yue WU,  Red Er CHEN,  Yong Min ZHANG. Reductive Cleavage of S-S Bond by Sm/NiCl2 or Sm/NiCl2·6H2O System:A New Method for the Preparation of Thiolesters[J]. Chinese Chemical Letters, 1999, 10(11): 899-902. shu
Citation:  Hua Yue WU,  Red Er CHEN,  Yong Min ZHANG. Reductive Cleavage of S-S Bond by Sm/NiCl2 or Sm/NiCl2·6H2O System:A New Method for the Preparation of Thiolesters[J]. Chinese Chemical Letters, 1999, 10(11): 899-902. shu

Reductive Cleavage of S-S Bond by Sm/NiCl2 or Sm/NiCl2·6H2O System:A New Method for the Preparation of Thiolesters

  • 基金项目:

    We are grateful to the National Natural Science Foundation of China (Project No.29872010)

    the NSF of Zhejiang Province, China, and the Laboratory of Organometallic Chemistry, Shanghai institute of Organic Chemistry, Chinese Academy of Sciences for financial support.

摘要: Disulfides were reduced by the Sm/NiCl2, or Sm/NiCl2·6H20 system to generate thiolate anion.which reacted further with anhydrides or acyl chlorides to afford thiolesters in good yields under mild and neutral conditions.

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  • 收稿日期:  1999-05-19
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