引用本文:
Ai Li BO, Xiang Qin LIN. In-situ FTIR Spectroelectrochemical Study of Chromium Hexacyanoferrate on Glassy Carbon Electrode[J]. Chinese Chemical Letters,
1998, 9(9): 851-854.
Citation: Ai Li BO, Xiang Qin LIN. In-situ FTIR Spectroelectrochemical Study of Chromium Hexacyanoferrate on Glassy Carbon Electrode[J]. Chinese Chemical Letters, 1998, 9(9): 851-854.
Citation: Ai Li BO, Xiang Qin LIN. In-situ FTIR Spectroelectrochemical Study of Chromium Hexacyanoferrate on Glassy Carbon Electrode[J]. Chinese Chemical Letters, 1998, 9(9): 851-854.
In-situ FTIR Spectroelectrochemical Study of Chromium Hexacyanoferrate on Glassy Carbon Electrode
摘要:
Chromium hexacyanoferrate (CrHCF) modified glassy carbon electrode (GC) in different electrolytes was studied by cyclic voltammetry and in situ FTIR spectroelectrochemistry. The results indicate that the behavior of CrHCF film can be understood in term of two structures: Cr1/3Cr(Ⅲ)Fe(Ⅱ)(CN)6 and MCr(Ⅲ)Fe(Ⅱ)(CN)6. Besides, the film exists in amorphous state: the outer layer is porous film, while the inner layer is relatively compact. According to the electrochemical reaction of CrHCF, the lattice can contract and expand with the cations' diffusion.
English
In-situ FTIR Spectroelectrochemical Study of Chromium Hexacyanoferrate on Glassy Carbon Electrode
Abstract:
Chromium hexacyanoferrate (CrHCF) modified glassy carbon electrode (GC) in different electrolytes was studied by cyclic voltammetry and in situ FTIR spectroelectrochemistry. The results indicate that the behavior of CrHCF film can be understood in term of two structures: Cr1/3Cr(Ⅲ)Fe(Ⅱ)(CN)6 and MCr(Ⅲ)Fe(Ⅱ)(CN)6. Besides, the film exists in amorphous state: the outer layer is porous film, while the inner layer is relatively compact. According to the electrochemical reaction of CrHCF, the lattice can contract and expand with the cations' diffusion.
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 0
- HTML全文浏览量: 0
下载:
