引用本文:
Jin Jun WANG, Chang Jin, YUE Jun QIU, Cang Yi QIAN. The Total Synthesis of (±)-Hinesol and (±)-Agarospirol[J]. Chinese Chemical Letters,
1997, 8(11): 957-960.
Citation: Jin Jun WANG, Chang Jin, YUE Jun QIU, Cang Yi QIAN. The Total Synthesis of (±)-Hinesol and (±)-Agarospirol[J]. Chinese Chemical Letters, 1997, 8(11): 957-960.
Citation: Jin Jun WANG, Chang Jin, YUE Jun QIU, Cang Yi QIAN. The Total Synthesis of (±)-Hinesol and (±)-Agarospirol[J]. Chinese Chemical Letters, 1997, 8(11): 957-960.
The Total Synthesis of (±)-Hinesol and (±)-Agarospirol
摘要:
A mild base-catalyzed retro-benzilic acid rearrangement of a proto-[2+2] photo-cycloadduct,formed in highly steroselective photoaddition of methyl 2,4-dioxo-pentanoate to 1,5-dimethyl-6-methylenecyclohexene,afforded a spiro[4,5] decenedione from which hinesol and agarospirol were synthesized by means of reductive elimination of α-diketone and C1-homologation.
English
The Total Synthesis of (±)-Hinesol and (±)-Agarospirol
Abstract:
A mild base-catalyzed retro-benzilic acid rearrangement of a proto-[2+2] photo-cycloadduct,formed in highly steroselective photoaddition of methyl 2,4-dioxo-pentanoate to 1,5-dimethyl-6-methylenecyclohexene,afforded a spiro[4,5] decenedione from which hinesol and agarospirol were synthesized by means of reductive elimination of α-diketone and C1-homologation.
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