引用本文:
Shou Jun XU, Kun Yuan QIU. SYNTHESIS OF BLOCK COPOLYMERS OF STYRENE AND N-(p-SUBSTITUTED PHENYL) MALEIMIDES BY ANIONIC POLYMERIZATION[J]. Chinese Chemical Letters,
1996, 7(4): 367-370.
Citation: Shou Jun XU, Kun Yuan QIU. SYNTHESIS OF BLOCK COPOLYMERS OF STYRENE AND N-(p-SUBSTITUTED PHENYL) MALEIMIDES BY ANIONIC POLYMERIZATION[J]. Chinese Chemical Letters, 1996, 7(4): 367-370.

Citation: Shou Jun XU, Kun Yuan QIU. SYNTHESIS OF BLOCK COPOLYMERS OF STYRENE AND N-(p-SUBSTITUTED PHENYL) MALEIMIDES BY ANIONIC POLYMERIZATION[J]. Chinese Chemical Letters, 1996, 7(4): 367-370.

SYNTHESIS OF BLOCK COPOLYMERS OF STYRENE AND N-(p-SUBSTITUTED PHENYL) MALEIMIDES BY ANIONIC POLYMERIZATION
摘要:
The block copolymers were synthesized by anionic polymerization via two steps reaction.First,styrene was initiated by n-butyl lithium,then maleimides were added into the living styrene system to obtain block copolymers.1H-NMR and FT-IR measurements indicated that block copolymers had been formed.From the results of thermogravimetric analysis,it could be concluded that the block copolymer had a much better thermal stability than random copolymers prepared by radical polymerization.Also the surface hydrophilicities of the two kinds of copolymers were compared.
English
SYNTHESIS OF BLOCK COPOLYMERS OF STYRENE AND N-(p-SUBSTITUTED PHENYL) MALEIMIDES BY ANIONIC POLYMERIZATION
Abstract:
The block copolymers were synthesized by anionic polymerization via two steps reaction.First,styrene was initiated by n-butyl lithium,then maleimides were added into the living styrene system to obtain block copolymers.1H-NMR and FT-IR measurements indicated that block copolymers had been formed.From the results of thermogravimetric analysis,it could be concluded that the block copolymer had a much better thermal stability than random copolymers prepared by radical polymerization.Also the surface hydrophilicities of the two kinds of copolymers were compared.

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