引用本文:
Xin CHEN, Yu Ping FENG, Nan Jing ZHANG, Yu Fen ZHAO. STRUCTURE ASSIGNMENT FOR EPIMERIC THYMIDINE-3'-YL BENZOIN PHOSPHATES[J]. Chinese Chemical Letters,
1995, 6(7): 577-580.
Citation: Xin CHEN, Yu Ping FENG, Nan Jing ZHANG, Yu Fen ZHAO. STRUCTURE ASSIGNMENT FOR EPIMERIC THYMIDINE-3'-YL BENZOIN PHOSPHATES[J]. Chinese Chemical Letters, 1995, 6(7): 577-580.
Citation: Xin CHEN, Yu Ping FENG, Nan Jing ZHANG, Yu Fen ZHAO. STRUCTURE ASSIGNMENT FOR EPIMERIC THYMIDINE-3'-YL BENZOIN PHOSPHATES[J]. Chinese Chemical Letters, 1995, 6(7): 577-580.
STRUCTURE ASSIGNMENT FOR EPIMERIC THYMIDINE-3'-YL BENZOIN PHOSPHATES
摘要:
Reaction of oxyphosphorane (1) with thymidine (2) followed by hydrolysis under mild conditions afforded TMP, TpT and thymidine-3'-yl benzoin phosphates (3).The structures of 3 were determined by 31P, 1H, 13C NMR and mass spectral data, and 31P-1H COSY experiments.The possible formation mechanism of 3 was also discussed.
English
STRUCTURE ASSIGNMENT FOR EPIMERIC THYMIDINE-3'-YL BENZOIN PHOSPHATES
Abstract:
Reaction of oxyphosphorane (1) with thymidine (2) followed by hydrolysis under mild conditions afforded TMP, TpT and thymidine-3'-yl benzoin phosphates (3).The structures of 3 were determined by 31P, 1H, 13C NMR and mass spectral data, and 31P-1H COSY experiments.The possible formation mechanism of 3 was also discussed.
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