引用本文:
Jing Hong LI, Guang Jin CHENG, Chang Wei LIU, Ju Guang JIN, Shao Jun DONG. A NOVEL IN-SITU SPECTROELECTROCHEMICAL TECHNIQUE WITH PROBE BEAM DEFLECTION:FOR STUDY OF THE ION EXCHANGE BETWEEN FILMS ON ELECTRODE SURFACE AND SOLUTIONS[J]. Chinese Chemical Letters,
1995, 6(11): 983-986.
Citation: Jing Hong LI, Guang Jin CHENG, Chang Wei LIU, Ju Guang JIN, Shao Jun DONG. A NOVEL IN-SITU SPECTROELECTROCHEMICAL TECHNIQUE WITH PROBE BEAM DEFLECTION:FOR STUDY OF THE ION EXCHANGE BETWEEN FILMS ON ELECTRODE SURFACE AND SOLUTIONS[J]. Chinese Chemical Letters, 1995, 6(11): 983-986.
Citation: Jing Hong LI, Guang Jin CHENG, Chang Wei LIU, Ju Guang JIN, Shao Jun DONG. A NOVEL IN-SITU SPECTROELECTROCHEMICAL TECHNIQUE WITH PROBE BEAM DEFLECTION:FOR STUDY OF THE ION EXCHANGE BETWEEN FILMS ON ELECTRODE SURFACE AND SOLUTIONS[J]. Chinese Chemical Letters, 1995, 6(11): 983-986.
A NOVEL IN-SITU SPECTROELECTROCHEMICAL TECHNIQUE WITH PROBE BEAM DEFLECTION:FOR STUDY OF THE ION EXCHANGE BETWEEN FILMS ON ELECTRODE SURFACE AND SOLUTIONS
摘要:
A novel in-situ spectroelectrochemical technique,the combination of probe beam deflection (PBD) with cyclic voltammetry (CV),was used to study the ion cxchange process of prussian blue (PB) modified film electrode in contact with various electrolyte solutions.The ion exchange mechanism was verified as following:K2Fe2+FeⅡ(CN)8???KFe3+FeⅡ(CN)8???[Fe3+FeⅢ(CN)8]x[KFe3+FeⅡ(CN)8]1-x where on reduction PB film in contact with an acidic KCl electrolyte,it was confirmed that protons enter into the PB film before K+ cations.
English
A NOVEL IN-SITU SPECTROELECTROCHEMICAL TECHNIQUE WITH PROBE BEAM DEFLECTION:FOR STUDY OF THE ION EXCHANGE BETWEEN FILMS ON ELECTRODE SURFACE AND SOLUTIONS
Abstract:
A novel in-situ spectroelectrochemical technique,the combination of probe beam deflection (PBD) with cyclic voltammetry (CV),was used to study the ion cxchange process of prussian blue (PB) modified film electrode in contact with various electrolyte solutions.The ion exchange mechanism was verified as following:K2Fe2+FeⅡ(CN)8???KFe3+FeⅡ(CN)8???[Fe3+FeⅢ(CN)8]x[KFe3+FeⅡ(CN)8]1-x where on reduction PB film in contact with an acidic KCl electrolyte,it was confirmed that protons enter into the PB film before K+ cations.
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