引用本文:
Xiang Dong ZHANG, Qi Tao LIU, Wen Hua TAN, Yu SONG. HEATS OF INTERACTION OF ORGANIC BASES WITH POLYMER PROTECTED CATALYST PVC-AlCl3[J]. Chinese Chemical Letters,
1994, 5(6): 533-536.
Citation: Xiang Dong ZHANG, Qi Tao LIU, Wen Hua TAN, Yu SONG. HEATS OF INTERACTION OF ORGANIC BASES WITH POLYMER PROTECTED CATALYST PVC-AlCl3[J]. Chinese Chemical Letters, 1994, 5(6): 533-536.
Citation: Xiang Dong ZHANG, Qi Tao LIU, Wen Hua TAN, Yu SONG. HEATS OF INTERACTION OF ORGANIC BASES WITH POLYMER PROTECTED CATALYST PVC-AlCl3[J]. Chinese Chemical Letters, 1994, 5(6): 533-536.
HEATS OF INTERACTION OF ORGANIC BASES WITH POLYMER PROTECTED CATALYST PVC-AlCl3
摘要:
Heats of immersion into a series of organic bases at 25℃ are reported for polymer protected catalyst PVC-AlCl3.There is a good correlation between the heats of immersion of PVC-AlCl3 and tbennochemical measurements of BF3 or SbCl5.The results have shown that the reaction of PVC-AlCl3 with various bases is essentially Lewis acid-base interaction and the surface acidity of PVC-AlCl3 is mainly attributed to Lewis acidity.
English
HEATS OF INTERACTION OF ORGANIC BASES WITH POLYMER PROTECTED CATALYST PVC-AlCl3
Abstract:
Heats of immersion into a series of organic bases at 25℃ are reported for polymer protected catalyst PVC-AlCl3.There is a good correlation between the heats of immersion of PVC-AlCl3 and tbennochemical measurements of BF3 or SbCl5.The results have shown that the reaction of PVC-AlCl3 with various bases is essentially Lewis acid-base interaction and the surface acidity of PVC-AlCl3 is mainly attributed to Lewis acidity.
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