引用本文:
谢素原, 张强, 黄荣彬, 郑兰荪. 等离子体反应合成全卤代芘[J]. 应用化学,
1998, 15(6): 61-64.
Citation: Xie Suyuan, Zhang Qiang, Huang Rongbin, Zheng Lansun. Synthesis of Perhalogenated Pyrene by Plasma Reaction[J]. Chinese Journal of Applied Chemistry, 1998, 15(6): 61-64.
Citation: Xie Suyuan, Zhang Qiang, Huang Rongbin, Zheng Lansun. Synthesis of Perhalogenated Pyrene by Plasma Reaction[J]. Chinese Journal of Applied Chemistry, 1998, 15(6): 61-64.
等离子体反应合成全卤代芘
English
Synthesis of Perhalogenated Pyrene by Plasma Reaction
Abstract:
A series of perhalogenated aromatic compounds were synthesized by arc-discharging of solid polytetrafluoroethylene and glow-discharge of chloroform vapor, respectively. Among the products, perchloropyrene(C16Cl10) and perfluoropyrene (C16F10) were separated and charac-terized. The features of the plasma reaction and product formation mechanism have been discussed. The products of the plasma reaction are normally a series of compounds with similar structure. Their formation appeared not to be affected by the compositions or structures of the reagents, as well as the discharge conditions.
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Key words:
- perchloropyrene
- / perfluoropyrene
- / plasma synthesis
- / arc-discharge
- / glow-discharge
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