引用本文:
李仲辉, 秦圣英, 李建章, 谢吉胜. 冠醚化对双Schiff碱钴(Ⅱ)配合物催化氧化性能的影响[J]. 应用化学,
1998, 15(5): 43-46.
Citation: Li Zhonghui, Qin Shengying, Li Jianzhang, Xie Jisheng. Effect of Crown Ring in Crowned Binary Schiff Base Cobalt(Ⅱ) Complex on Its Catalytic Oxidation Activity[J]. Chinese Journal of Applied Chemistry, 1998, 15(5): 43-46.
Citation: Li Zhonghui, Qin Shengying, Li Jianzhang, Xie Jisheng. Effect of Crown Ring in Crowned Binary Schiff Base Cobalt(Ⅱ) Complex on Its Catalytic Oxidation Activity[J]. Chinese Journal of Applied Chemistry, 1998, 15(5): 43-46.
冠醚化对双Schiff碱钴(Ⅱ)配合物催化氧化性能的影响
English
Effect of Crown Ring in Crowned Binary Schiff Base Cobalt(Ⅱ) Complex on Its Catalytic Oxidation Activity
Abstract:
Crowned Schiff's base cobalt(Ⅱ) complex 1c and its analogues 1a and 1b were synthesized and their catalytic activities in cumene oxidation to cumyl hydroperoxide have been compared. The results showing that complex 1c being superior to its analogues in catalytic activity are explained in terms of their oxygen adduction constants.
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Key words:
- crown ether
- / Schiff base
- / cobalt complex
- / synthesis
- / catalytic oxidation
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