酸性离子液体降解纤维素制备5-羟甲基糠醛的研究

付霓虹 袁玉国 王景芸 臧树良

引用本文: 付霓虹, 袁玉国, 王景芸, 臧树良. 酸性离子液体降解纤维素制备5-羟甲基糠醛的研究[J]. 化学通报, 2016, 79(4): 355-359. shu
Citation:  Fu Nihong, Yuan Yuguo, Wang Jingyun, Zang Shuliang. Preparation of 5-Hydroxymethylfurfural from Cellulose Degradation Catalyzed by Acidic Ionic Liquids[J]. Chemistry, 2016, 79(4): 355-359. shu

酸性离子液体降解纤维素制备5-羟甲基糠醛的研究

    通讯作者: 王景芸,女,博士生,讲师,从事生物质转化研究,,E-mail:wangjingyun0713@163.com
  • 基金项目:

    中国石油化工股份有限公司科技项目(41405F)资助 

摘要: 以离子液体氯化1-烯丙基-3-甲基咪唑鎓([Amim]Cl)为溶剂,以咪唑类酸功能离子液体[Cnmim]HSO4n=2,4,6,8)和CrCl3·6H2O为复合催化剂,在微波辅助加热条件下降解纤维素制备5-羟甲基糠醛(5-HMF),考察了催化剂加入量、反应温度、催化剂种类、反应时间、加水量等反应条件对纤维素降解反应的影响。结果表明,当[C2mim]HSO4的加入量为0.02g、微晶纤维素(MCC)和CrCl3·6H2O的摩尔比为10:1、反应温度为160℃、反应时间为30min、加水量为50μL时,微晶纤维素转化率为100%,总还原糖收率为87.2%,5-HMF产率最高可达到50%。

English

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  • 收稿日期:  2015-07-06
  • 网络出版日期:  2015-10-10
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