In this study, ZnSnO₃/NiO heterostructures were synthesized using a co-precipitation method followed by an annealing process. The gas-sensitive characteristics of the sensors based on these samples were evaluated. The results indicate that the sensor performance was optimized when the molar ratio of Ni to Zn was 1∶2. Specifically, the response values of the ZnSnO₃/NiO-2-based sensor to 100 μL·L^-1 triethylamine (TEA) gas at 220 ℃ reached 70.6, which were 6.1 times higher than that of the pure ZnSnO₃ based sensor. The findings demonstrate that ZnSnO₃/NiO heterostructures exhibited not only short response and recovery times (1 s/18 s) but also good gas selectivity, repeatability, and long-term stability. The enhanced sensing mechanism has been investigated in detail.

聚N-异丙基丙烯酰胺(PNIPAm)交联温敏纳米纤维膜作为一种相变温度易于控制的新兴响应性材料，克服了传统PNIPAm块状水凝胶的生产成本高、响应速率慢和PNIPAm非交联温敏纳米纤维耐水性差的缺点，受到广泛研究并应用于智能开关、温度致动器、水油分离、药物、细胞控制释放和伤口敷料等领域。形貌稳定性和快速响应性是温敏纳米纤维膜在重复体积变化过程中最大的挑战，同时也作为评价PNIPAm温敏纳米纤维膜的实用性最重要指标引起了人们广泛的关注。本文全面综述了PNIPAm温敏纳米纤维膜近二十年来国内外的突破性进展和非交联作用下PNIPAm温敏纳米纤维膜的形貌变化和响应性，重点综合分析了物理和化学交联中交联反应类型、交联度、交联时间和交联分子量对PNIPAm温敏纳米纤维膜的形貌稳定性和响应行为的影响，为之后纤维膜的交联处理提供了理论支持，并对PNIPAm温敏纳米纤维膜的发展及应用前景进行了展望。

Herein, an FMS/CC composite was successfully fabricated by depositing FeMoS₄ onto a pristine carbon fiber cloth (CC) substrate via a facile two-step hydrothermal method. The amorphous nature of the FMS/CC composite endows it with abundant catalytically active sites, thereby accelerating the reduction of I₃^-. More importantly, the dye-sensitized solar cells (DSSCs) prepared by scraping it on flexible titanium mesh with low resistance had low series resistance (R_s). Electrochemical characterizations revealed that the DSSCs employing the FMS/CC counter electrode achieved a power conversion efficiency (PCE) of ca. 9.51% (surpassing the ca. 8.15% efficiency of the Pt counter electrode), open-circuit voltage (V_oc) of ca. 0.79 V, short-circuit current density (J_sc) of ca. 18.31 mA·cm^-2, and fill factor (FF) of ca. 0.65. Moreover, after 100 times of cyclic voltammetry (CV) test, the CV curve remainedunchanged, indicating the excellent stability of FMS/CC in the electrolyte containing I^3-/I^-.

面向化学类(非高分子)专业的高分子化学实验教学发展较为缓慢，亟需紧跟研究前沿，引入新内容。本文总结了近十年的教学改革经验，并以温敏型高分子的制备、溶液性质、光学性能与应用为例，介绍如何通过实验教学内容、实验技术、教学方法等方面的创新，设计符合理科人才培养需求的、契合时代与科学发展的、被学生喜爱与重视的一系列高分子化学实验，以有效解决培养需求与课业负担之间的矛盾，且在不新增开课、课时有限的情况下，加入到化学类专业本科教学体系中，激发学生对学科领域的兴趣，提升学生的探究和创新能力。

免疫治疗已成癌症治疗的研究热点，癌症纳米疫苗作为该领域的代表性治疗方式取得了显著进展。然而，免疫原性低、抗原递送效率不足、免疫应答效果差等问题限制了免疫治疗的发展。为解决这些局限性，本研究通过绿色水热法合成枸杞衍生碳点(Lyc-CDs)，并基于此开发了一种pH响应性纳米疫苗(Lyc-OVA)。由于保留了枸杞多糖(LBP，总含糖量18.43%)，Lyc-CDs对卵清蛋白(OVA)表现出优异的负载效率(48.40%)和pH响应释放特性(在pH 5.4条件下，OVA在24 h内的释放率为80%)。分子对接模拟表明，LBP单糖(鼠李糖/半乳糖)与OVA之间存在氢键和π-阳离子相互作用。Lyc-OVA可促进树突状细胞成熟(CD80⁺CD86⁺占比32.87%，与脂多糖(LPS)相当)并诱导细胞因子分泌(肿瘤坏死因子-α (TNF-α)：13.10 pg mL⁻¹；干扰素-γ (IFN-γ)：17.78 pg mL⁻¹；白细胞介素-6 (IL-6)：3.74 pg mL⁻¹)。在双侧B16-OVA黑色素瘤模型中，Lyc-OVA通过激活CD4⁺CD8⁺T细胞、减少免疫抑制性调节性T细胞(Treg)/髓系来源抑制细胞(MDSC)群体及重塑肿瘤免疫微环境，抑制原发/远端肿瘤生长(抑制率分别为80.36%/82.16%)。本研究揭示了天然多糖在纳米疫苗中的多功能作用，为肿瘤免疫治疗提供了有效策略。