采用气固法制备了磷化钼-碳纳米花(MoP-CFs)，通过简单的超声自组装将C₆₀修饰在MoP-CFs表面，形成范德瓦耳斯异质结。研究其电催化析氢性能发现，C₆₀的修饰能够有效降低电催化析氢过电位。其中，10% C₆₀-MoP-CFs样品(10%为C₆₀的质量分数)表现出最佳催化活性，在酸性和碱性条件下达到10 mA·cm^-2的电流密度时，所需要的过电位分别为158和157 mV，并且具有至少20 h的电催化稳定性。C₆₀与MoP-CFs之间强电子耦合作用促进电子由C₆₀迁移到MoP-CFs表面，有助于减小电荷传输阻力，加快电催化析氢界面反应动力学过程。

A new metal-organic framework (MOF) {[Cd(L)_0.5(4, 4'-bpy)_0.5]·H₂O}_n (1), where H₄L=(1, 1': 4', 1″-terphenyl)-2, 2″, 4, 4″-tetracarboxylic acid, 4, 4'-bpy=4, 4'-bipyridine, was synthesized by hydro-solvothermal method. The structure of complex 1 was characterized by single-crystal X-ray diffraction, elemental analysis, powder X-ray diffraction, thermogravimetric analysis, and infrared spectrum analysis. The analysis of single crystal structure shows that 1 is a 3D structure, belonging to the monoclinic crystal system, C2/c space group. Cd(Ⅱ) connects L^4- and 4, 4'-bpy to form a 2D plane structure, and the layers are connected by L^4- to form a 3D network structure. The MOF shows good stability and can be used for the detection of tetracycline (TET) and p-nitrophenol (4-NP) by fluorescence quenching. The detection limits of TET and 4-NP were 0.15 and 0.062 μmol·L^-1, respectively. In addition, the fluorescence quenching mechanism of 1 was also studied. 1 can be successfully applied to the determination of TET and 4-NP content in Yanhe water samples.