产教融合下“现代分析技术”课程改革与实践
温聪颖, 杜正坤, 卢玉坤, 王宗廷, 何化, 杨丽敏, 曾景斌
【大学化学】doi: 10.3866/PKU.DXHX202312089
本文在科产教融合理念下,对“现代分析技术”进行了课程改革。主要基于校内/际/企合作实现优质师资共享,通过融入科学前沿和生产实际丰富教学内容,在授课中采用教师主导、学生自主探究、“理虚实”结合、线上线下协同、公众号辅助等多维教学模式,同时配备多元化考核评价体系促学促教。实践结果表明,教学质量得到了明显提升,极大地助力于理论知识、科学研究、生产实践兼顾兼优的复合型人才的培养。
关键词: 现代分析技术, 教学改革, 科产教融合, 复合型人才
Z型异质结Cu2O/Bi2MoO6的构建及光催化降解性能
赵强, 郭智楠, 李淑英, 王俊丽, 李作鹏, 贾治芳, 王科伟, 郭永
【无机化学学报】doi: 10.11862/CJIC.20230435
通过水热法制备出一系列Z型异质结Cu2O/Bi2MoO6新型光催化剂。采用扫描电子显微镜、粉末X射线衍射、红外光谱、紫外可见吸收光谱等表征手段研究了催化剂的形貌、结构性质和光电化学性质,并以四环素(TC)为降解目标污染物,进一步探究了其催化效率。实验结果表明,Cu2O的加入提高了复合催化剂的光催化性能,其中20% Cu2O/Bi2MoO6复合催化剂(Cu2O和Bi2MoO6的质量比为20%)降解效果最好,100 min内可降解95%的TC。Cu2O与Bi2MoO6之间的协同作用使其可以吸收更多的可见光,所构建的Z型异质结改变了电子转移途径,提高了电子与空穴的分离效率,光催化活性显著提高。通过自由基捕获实验和能带结构,分析了Z型异质结Cu2O/Bi2MoO6复合催化剂光催化降解TC可能的机理。
关键词: 光催化剂, 钼酸铋, 氧化亚铜, Cu2O/Bi2MoO6, Z型异质结, 四环素
Cu2O/Bi2CrO6 Z-scheme heterojunction: Construction and photocatalytic degradation properties for tetracycline
Zhinan GUO, Junli WANG, Qiang ZHAO, Zhifang JIA, Zuopeng LI, Kewei WANG, Yong GUO
【无机化学学报】doi: 10.11862/CJIC.20240403
The Z-scheme heterojunction Cu2O/Bi2CrO6 photocatalyst was successfully prepared by introducing Cu2O on the Bi2CrO6 surface using a coprecipitation method. The photocatalytic degradation of tetracycline (TC) on Cu2O/Bi2CrO6 under visible light irradiation was investigated. It was found that the Cu2O/Bi2CrO6 photocatalyst had the best photocatalytic activity when the mass ratio of Cu2O to Bi2CrO6 was 20%, and the TC could be degraded by 87.5% within 100 min, which was about 1.8 times and 1.3 times higher than that of pure Bi2CrO6 and pure Cu2O, respectively. Besides, the Cu2O/Bi2CrO6 photocatalyst also showed good stability and reusability. The Z scheme heterojunction structure of Cu2O/Bi2CrO6 provided increased active sites, enhanced interfacial charge separation, and improved separation efficiency of photogenerated electro-hole (e--h+) pairs, leading to enhanced photocatalytic properties. Electron paramagnetic resonance (EPR) measurement confirmed that the superoxide radical (·O2-), hydroxyl radical (·OH), and h+ were the primary active species during photocatalysis.
关键词: photocatalyst, Cu2O, bismuth chromate, photocatalytic degradation, tetracycline

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