钙钛矿CsPbBr3薄膜的制备及其光电性能表征
师鑫源, 蒋晨阳, 翟长玉, 鲁雪梅, 李佳, 毛竹
【大学化学】doi: 10.3866/PKU.DXHX202312019
本实验是针对本科生能力水平、结合光伏领域前沿设计的一个化学综合实验。本实验采用简单的旋涂法在导电玻璃表面制备CsPbBr3钙钛矿薄膜材料,并创新性地将光探测器件的组装实验加入其中以研究CsPbBr3薄膜的光电性能。学生可在实验过程中肉眼可见地观察到黄色的CsPbBr3材料在紫外激光照射下发射出强烈的绿光,这一实验现象能够有效地激发学生兴趣。
关键词: 钙钛矿CsPbBr3, 光致发光, 光电转换, 光电流
Enhanced photocatalytic tetracycline degradation via 2D CdS/Ti3AlC2 MAX heterostructure
Qi HUANG, Youyi WANG, Zhujian MAO, Zhonghui YE, Weihan CHEN, Jui-yeh RAU, Jian HUANG
【无机化学学报】doi: 10.11862/CJIC.20250159
The CdS/Ti3AlC2 heterojunction photocatalyst was synthesized by the hydrothermal method, and its structure and performance were systematically analyzed through various characterization methods, including X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS), and photoluminescence (PL) spectroscopy, etc. The results confirmed the successful construction of the composite material and its excellent charge separation ability. Under ultraviolet light irradiation, the photocatalytic degradation performance of tetracycline was studied, and its degradation mechanism was clarified, among which the superoxide radical (·O2-) was the main active species. Under the conditions of pH=7 and catalyst dosage of 0.1 g·L-1, CdS/Ti3AlC2 exhibited excellent photocatalytic performance, with a TC degradation efficiency as high as 96.3%.
关键词: photocatalysis, heterostructures, tetracycline, CdS, Ti3AlC2

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