正名奖学金成立谈李先生的爱国奉献精神
王建国
【大学化学】doi: 10.12461/PKU.DXHX202412089
李正名院士是我国著名的教育家、化学家和农药学家。在李先生逝世3周年之际,李正名奖学金捐赠暨首届颁奖仪式在南开大学举行。本文结合一部分典型的具体事例,对李正名先生的教育家精神和科学家精神进行了介绍,从中折射出他始终如一的坚定爱国信念和无私奉献精神。青年学子通过学习李先生的光辉事迹,可以深入了解老一辈科学家浓厚的家国情怀。本文有助于激励当代大学生厚植爱国主义理想与信念,增强自主创新意识和能力,立志为中华民族的伟大复兴贡献自己的全部力量。
关键词: 李正名奖学金, 教育家精神, 科学家精神, 家国情怀
课程思政引领下的分析化学教学改革与实践
李甜, 张莉萍, 刘玲, 李瑞芳, 毛龙飞, 杨晖
【大学化学】doi: 10.3866/PKU.DXHX202310014
针对分析化学课程传统教学模式的痛点,以课程思政为契机,对课程实施教学改革。阐述了分析化学课程思政建设的总体思路,从重修教学大纲、重构教学内容、改革教学模式、改革课程考核方式等多方位协同进行。通过线上线下混合式教学改革,使教师的价值引领与学生的深度参与同步进行,实现知识传授、能力培养和价值塑造三位一体的培养目标。
关键词: 分析化学, 课程思政, 混合式教学, 教学改革
Influence of the loading methods of Ni species in Ni/CeO2 catalysts on the performance of CO methanation
Runran WANG, Qiyue JIAO, Ruifang LI, Hong WANG, Hongwei WANG, Yali BAO, Qi WANG, Xiaoyan WANG
【无机化学学报】doi: 10.11862/CJIC.20250364
To enhance the low-temperature activity and anti-sintering performance of Ni-based catalysts for CO methanation, mesoporous CeO2 supports with a confined structure were synthesized via a hydrothermal method. The effects of three Ni loading methods—incipient wetness impregnation, co-precipitation, and bis(cyclopentadienyl)nickel sublimation—on catalytic performance were systematically compared. Characterization techniques, including X-ray diffraction (XRD), N2 adsorption-desorption test, hydrogen temperature-programmed reduction (H2-TPR), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM), revealed the critical influence of the loading method on Ni species dispersion, particle size, and metal-support interaction. The results indicated that all three mesoporous Ni/CeO2 catalysts exhibited excellent anti-sintering properties due to the confinement effect of the support. However, their low-temperature activities differed significantly, primarily determined by the specific state of Ni. In the NC-B catalyst prepared by bis(cyclopentadienyl)nickel sublimation, the interaction between Ni species and the support was relatively weak. After reduction, this method yielded highly dispersed metallic Ni nanoparticles, increasing the number of low-temperature active sites. Consequently, the NC-B catalyst achieved 98% CO conversion rate and 100% CH4 selectivity at 300 ℃, demonstrating the optimal low-temperature methanation performance.
关键词: CO methanation, CeO2, Ni-based catalyst, anti-sintering, metal-support interaction

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