【大学化学】doi: 10.12461/PKU.DXHX202412089
李正名院士是我国著名的教育家、化学家和农药学家。在李先生逝世3周年之际,李正名奖学金捐赠暨首届颁奖仪式在南开大学举行。本文结合一部分典型的具体事例,对李正名先生的教育家精神和科学家精神进行了介绍,从中折射出他始终如一的坚定爱国信念和无私奉献精神。青年学子通过学习李先生的光辉事迹,可以深入了解老一辈科学家浓厚的家国情怀。本文有助于激励当代大学生厚植爱国主义理想与信念,增强自主创新意识和能力,立志为中华民族的伟大复兴贡献自己的全部力量。
【无机化学学报】doi: 10.11862/CJIC.20240320
Sulfur-doped iron-cobalt tannate nanorods (S-FeCoTA) derived from metal-organic frameworks (MOFs) as electrocatalysts were synthesized via a one-step hydrothermal method. The optimized S-FeCoTA was interlaced by loose nanorods, which had many voids. The S-FeCoTA catalysts exhibited excellent electrochemical oxygen evolution reaction (OER) performance with a low overpotential of 273 mV at 10 mA·cm-2 and a small Tafel slope of 36 mV·dec-1 in 1 mol·L-1 KOH. The potential remained at 1.48 V (vs RHE) at 10 mA·cm-2 under continuous testing for 15 h, implying that S-FeCoTA had good stability. The Faraday efficiency of S-FeCoTA was 94%. The outstanding OER activity of S-FeCoTA is attributed to the synergistic effects among S, Fe, and Co, thus promoting electron transfer, reducing the reaction kinetic barrier, and enhancing the OER performance.
