正名奖学金成立谈李先生的爱国奉献精神
王建国
【大学化学】doi: 10.12461/PKU.DXHX202412089
李正名院士是我国著名的教育家、化学家和农药学家。在李先生逝世3周年之际,李正名奖学金捐赠暨首届颁奖仪式在南开大学举行。本文结合一部分典型的具体事例,对李正名先生的教育家精神和科学家精神进行了介绍,从中折射出他始终如一的坚定爱国信念和无私奉献精神。青年学子通过学习李先生的光辉事迹,可以深入了解老一辈科学家浓厚的家国情怀。本文有助于激励当代大学生厚植爱国主义理想与信念,增强自主创新意识和能力,立志为中华民族的伟大复兴贡献自己的全部力量。
关键词: 李正名奖学金, 教育家精神, 科学家精神, 家国情怀
偏铝酸锂/环化聚丙烯腈共包覆改性高镍层状正极材料的制备
刘君珂, 郑坤贵, 孙雯静, 白高杨, 白国栋, 尹祖伟, 周尧, 李君
【无机化学学报】doi: 10.11862/CJIC.20240189
构建表面无机-有机复合包覆层,用于改善高镍层状(NCM811)正极材料结构和界面不稳定问题。复合包覆层由纳米偏铝酸锂(LiAlO2,LAO)和环化聚丙烯腈(cPAN)构成。该复合包覆层中LAO是一种典型的锂离子导体,可提供Li+迁移通道;PAN环化后,可产生离域的π键,形成具有电子导电性的cPAN。材料表面复合包覆层的结构及成分研究表明,该复合包覆层均匀分布在NCM811材料表面。半电池测试结果表明,在2.7~4.3 V(vs Li/Li+)电压范围内,在180 mA·g-1电流密度下,改性后的NCM811材料循环150周后容量保持率为84.8%。而同样条件下,原始NCM811材料容量保持率为65.5%。该复合包覆层可有效提升NCM811结构和界面稳定性,减少电解液分解,降低界面阻抗。
关键词: 锂离子电池, 高镍层状正极, 复合包覆, 界面稳定性, 离子电导率
Synergistic nitrogen doping and carbon support in TiO2 for enhanced photocatalytic degradation of methylene blue and oxytetracycline
Ruru MA, Yingjie SONG, Yahui LI, Ermin ZHOU, Deqiang LI, Xiaojuan HUANG, Jun LI
【无机化学学报】doi: 10.11862/CJIC.20250221
In this study, sawdust served as a carbon source and urea as a nitrogen source to synthesize carbon- supported, nitrogen-doped TiO2 composites via a one-pot solvothermal method. The composites were characterized using FTIR, powder X-ray diffraction, X-ray photoelectron spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy, thermogravimetry-derivative thermogravimetry, scanning electron microscopy-energy dispersive spectroscopy, and transmission electron microscopy. Results indicated that all synthesized composites exhibit the anatase phase, with those calcined at 800 ℃ demonstrating enhanced crystallinity. Nitrogen is incorporated into the TiO2 lattice, while carbon is predominantly located on the surface. Photodegradation experiments showed that 20 mg of composite N-TiO2/C-800 achieved degradation rates of 93.4% for methylene blue (20 mg·L-1, 50 mL) and 99.4% for oxytetracycline (20 mg·L-1, 50 mL) within 30 min. Free radical capture experiments indicated that h+ was the primary active species in the photocatalytic degradation process.
关键词: N-TiO2/C, photocatalysis, visible light, methylene blue, oxytetracycline, degradation

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