Effect of Silyl Moiety on the Reaction of O,O'-Phenylenephosphoryl Chloride with N-Silylvaline Silyl Ester

Qian WANG Hai Yan LU Yu Fen ZHAO

引用本文: Qian WANG,  Hai Yan LU,  Yu Fen ZHAO. Effect of Silyl Moiety on the Reaction of O,O'-Phenylenephosphoryl Chloride with N-Silylvaline Silyl Ester[J]. Chinese Chemical Letters, 1997, 8(12): 1017-1018. shu
Citation:  Qian WANG,  Hai Yan LU,  Yu Fen ZHAO. Effect of Silyl Moiety on the Reaction of O,O'-Phenylenephosphoryl Chloride with N-Silylvaline Silyl Ester[J]. Chinese Chemical Letters, 1997, 8(12): 1017-1018. shu

Effect of Silyl Moiety on the Reaction of O,O'-Phenylenephosphoryl Chloride with N-Silylvaline Silyl Ester

  • 基金项目:

    We thank the financial support of the National Natural Science Foundation of China and the National Science and Technology Committee.

摘要: N-Trimethylsilylvaline trimethylsilyl ester Ⅱa,N-triethylsilylvaline triethylsilyl ester Ⅱb and N-tert-butyldimethylsilylvaline tert-butyldimethylester Ⅱc showed evidently different reactivities with O,O'-phenylenephosphorylchloride.The formation speed of the final spiro-bicyclic pentacoordinated phosphorus compounds depends on the intramolecular transfer ability of the silyl oiety crucially.

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  • 收稿日期:  1997-08-20
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