引用本文:
Qian WANG, Hai Yan LU, Yu Fen ZHAO. Effect of Silyl Moiety on the Reaction of O,O'-Phenylenephosphoryl Chloride with N-Silylvaline Silyl Ester[J]. Chinese Chemical Letters,
1997, 8(12): 1017-1018.
Citation: Qian WANG, Hai Yan LU, Yu Fen ZHAO. Effect of Silyl Moiety on the Reaction of O,O'-Phenylenephosphoryl Chloride with N-Silylvaline Silyl Ester[J]. Chinese Chemical Letters, 1997, 8(12): 1017-1018.
Citation: Qian WANG, Hai Yan LU, Yu Fen ZHAO. Effect of Silyl Moiety on the Reaction of O,O'-Phenylenephosphoryl Chloride with N-Silylvaline Silyl Ester[J]. Chinese Chemical Letters, 1997, 8(12): 1017-1018.
Effect of Silyl Moiety on the Reaction of O,O'-Phenylenephosphoryl Chloride with N-Silylvaline Silyl Ester
摘要:
N-Trimethylsilylvaline trimethylsilyl ester Ⅱa,N-triethylsilylvaline triethylsilyl ester Ⅱb and N-tert-butyldimethylsilylvaline tert-butyldimethylester Ⅱc showed evidently different reactivities with O,O'-phenylenephosphorylchloride.The formation speed of the final spiro-bicyclic pentacoordinated phosphorus compounds Ⅳ depends on the intramolecular transfer ability of the silyl oiety crucially.
English
Effect of Silyl Moiety on the Reaction of O,O'-Phenylenephosphoryl Chloride with N-Silylvaline Silyl Ester
Abstract:
N-Trimethylsilylvaline trimethylsilyl ester Ⅱa,N-triethylsilylvaline triethylsilyl ester Ⅱb and N-tert-butyldimethylsilylvaline tert-butyldimethylester Ⅱc showed evidently different reactivities with O,O'-phenylenephosphorylchloride.The formation speed of the final spiro-bicyclic pentacoordinated phosphorus compounds Ⅳ depends on the intramolecular transfer ability of the silyl oiety crucially.
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