Structural Studies of 3-(1,2-O-Isopropylidene-α-D-xylosyl)-5-phenyl-1,2,4-oxadiazole

Ming Long ZHANG Yu Xin CUI Ling Tai MA Li He Zhang Yang LU Bin ZHAO Qi Tai ZHENG

引用本文: Ming Long ZHANG,  Yu Xin CUI,  Ling Tai MA,  Li He Zhang,  Yang LU,  Bin ZHAO,  Qi Tai ZHENG. Structural Studies of 3-(1,2-O-Isopropylidene-α-D-xylosyl)-5-phenyl-1,2,4-oxadiazole[J]. Chinese Chemical Letters, 1999, 10(2): 117-120. shu
Citation:  Ming Long ZHANG,  Yu Xin CUI,  Ling Tai MA,  Li He Zhang,  Yang LU,  Bin ZHAO,  Qi Tai ZHENG. Structural Studies of 3-(1,2-O-Isopropylidene-α-D-xylosyl)-5-phenyl-1,2,4-oxadiazole[J]. Chinese Chemical Letters, 1999, 10(2): 117-120. shu

Structural Studies of 3-(1,2-O-Isopropylidene-α-D-xylosyl)-5-phenyl-1,2,4-oxadiazole

  • 基金项目:

    We thanks the National Natural Science Foundation of China for financial support.

摘要: 1,2-O-Isopropylidene-3-C-cyano-5-O-benzoyl-α-D-xylose 2 was prepared stereoselectively from 1,2-O-isopropylidene-3-oxo-5-O-benzoyl-α-D-xylose 1. The structure of 2 was studied by two-dimensional NMR spectroscopy in conjunction with X-ray crystallography of its corresponding 5-phenyl-1.2,4-oxadiazole isocarbonucleoside derivative 3. The absolute configurations of 2 and 3, and conformation of 3 are described herein.

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  • 收稿日期:  1998-11-19
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