引用本文:
Li Hua LIU, Zhi Qiang LIU, Zhu Qing GONG. Reactivity Ratios of Diethyldiallylammonium Chloride with Acrylamide or Acrylic Acid[J]. Chinese Chemical Letters,
2006, 17(11): 1523-1526.
Citation: Li Hua LIU, Zhi Qiang LIU, Zhu Qing GONG. Reactivity Ratios of Diethyldiallylammonium Chloride with Acrylamide or Acrylic Acid[J]. Chinese Chemical Letters, 2006, 17(11): 1523-1526.
Citation: Li Hua LIU, Zhi Qiang LIU, Zhu Qing GONG. Reactivity Ratios of Diethyldiallylammonium Chloride with Acrylamide or Acrylic Acid[J]. Chinese Chemical Letters, 2006, 17(11): 1523-1526.
Reactivity Ratios of Diethyldiallylammonium Chloride with Acrylamide or Acrylic Acid
摘要:
The compositions of copolymers of diethyldiallylammonium chloride (DEDAAC) with acrylamide (AM), acrylic acid (AA) or sodium acrylic acid (NaAA) at low conversion were determined by elemental analysis, and the reactivity ratios of monomers in copolymerization were obtained by Kelen-Tudos method. The results showed that the reactivity ratios rDE and rAM are 0.31 and 5.27 for DEDAAC with AM, rDE and rAA are 0.28 and 5.15 for DEDAAC with AA, and rDE and rNaAA are 0.40 and 3.97 for DEDAAC with NaAA, respectively. The copolymerizations for DEDAAC with AM, AA or NaAA are non-ideal copolymerization and the products are random copolymers.
English
Reactivity Ratios of Diethyldiallylammonium Chloride with Acrylamide or Acrylic Acid
Abstract:
The compositions of copolymers of diethyldiallylammonium chloride (DEDAAC) with acrylamide (AM), acrylic acid (AA) or sodium acrylic acid (NaAA) at low conversion were determined by elemental analysis, and the reactivity ratios of monomers in copolymerization were obtained by Kelen-Tudos method. The results showed that the reactivity ratios rDE and rAM are 0.31 and 5.27 for DEDAAC with AM, rDE and rAA are 0.28 and 5.15 for DEDAAC with AA, and rDE and rNaAA are 0.40 and 3.97 for DEDAAC with NaAA, respectively. The copolymerizations for DEDAAC with AM, AA or NaAA are non-ideal copolymerization and the products are random copolymers.
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