引用本文:
Shu Tang LIU, Xiang HU, Qi Wang LIU, Wen Tao ZHANG. SYNTHESIS AND STRUTURE OF THE FIRST INTERSTITIAL μ7-S CLUSTER Co7(μ7-S)(μ4-PSEt)(μ-SEt)2(μ-CO)2(CO)12[J]. Chinese Chemical Letters,
1991, 2(4): 335-338.
Citation: Shu Tang LIU, Xiang HU, Qi Wang LIU, Wen Tao ZHANG. SYNTHESIS AND STRUTURE OF THE FIRST INTERSTITIAL μ7-S CLUSTER Co7(μ7-S)(μ4-PSEt)(μ-SEt)2(μ-CO)2(CO)12[J]. Chinese Chemical Letters, 1991, 2(4): 335-338.
Citation: Shu Tang LIU, Xiang HU, Qi Wang LIU, Wen Tao ZHANG. SYNTHESIS AND STRUTURE OF THE FIRST INTERSTITIAL μ7-S CLUSTER Co7(μ7-S)(μ4-PSEt)(μ-SEt)2(μ-CO)2(CO)12[J]. Chinese Chemical Letters, 1991, 2(4): 335-338.
SYNTHESIS AND STRUTURE OF THE FIRST INTERSTITIAL μ7-S CLUSTER Co7(μ7-S)(μ4-PSEt)(μ-SEt)2(μ-CO)2(CO)12
摘要:
The reaction of Co2(CO)8 with EtSPCl2 gives a new crystal like compound Co7(μ7-S)(μ4-PSEt)(μ-SEt)2(μ-CO)2(CO)12,whose structure has been determined by single crystal x-ray diffraction.This special compound reveals some new features in cluster chemistry1:The fragmentation of a ligand precursor EtSPCl2 yieldsthree kinds of fragments,μ7-S,μ4-PSEt and μ-SEt,which are ligands in the same cluster molecule.There is a new type of bridging S presented——A μ7-S atom is interspaced into seven Co core.
English
SYNTHESIS AND STRUTURE OF THE FIRST INTERSTITIAL μ7-S CLUSTER Co7(μ7-S)(μ4-PSEt)(μ-SEt)2(μ-CO)2(CO)12
Abstract:
The reaction of Co2(CO)8 with EtSPCl2 gives a new crystal like compound Co7(μ7-S)(μ4-PSEt)(μ-SEt)2(μ-CO)2(CO)12,whose structure has been determined by single crystal x-ray diffraction.This special compound reveals some new features in cluster chemistry1:The fragmentation of a ligand precursor EtSPCl2 yieldsthree kinds of fragments,μ7-S,μ4-PSEt and μ-SEt,which are ligands in the same cluster molecule.There is a new type of bridging S presented——A μ7-S atom is interspaced into seven Co core.
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