A new free recoverable and reusable mono-alkaloid-type ligand and its use in preparation of ethyl (2R,3S)-2,3-dihydroxy-3-phenylpropionate

Qiao Feng Wang ,  Hui Chen ,  Yan Zhao ,  Xiao Ye Li ,  Sheng Yong Zhang

引用本文: Qiao Feng Wang,  Hui Chen,  Yan Zhao,  Xiao Ye Li,  Sheng Yong Zhang. A new free recoverable and reusable mono-alkaloid-type ligand and its use in preparation of ethyl (2R,3S)-2,3-dihydroxy-3-phenylpropionate[J]. Chinese Chemical Letters, 2009, 20(7): 763-766. doi: 10.1016/j.cclet.2009.02.018 shu
Citation:  Qiao Feng Wang,  Hui Chen,  Yan Zhao,  Xiao Ye Li,  Sheng Yong Zhang. A new free recoverable and reusable mono-alkaloid-type ligand and its use in preparation of ethyl (2R,3S)-2,3-dihydroxy-3-phenylpropionate[J]. Chinese Chemical Letters, 2009, 20(7): 763-766. doi: 10.1016/j.cclet.2009.02.018 shu

A new free recoverable and reusable mono-alkaloid-type ligand and its use in preparation of ethyl (2R,3S)-2,3-dihydroxy-3-phenylpropionate

  • 基金项目:

    This work was supported by the National Natural Science Foundation of China (No.20572131,20842007) and Natural Science Basic Research Plan in Shaanxi Province of China (No.SJ08-ZT02) for financial support.

摘要: A new free recoverable and reusable mono-alkaloid-type ligand has been synthesized by a simple method. With highly polar groups, the ligand can be recycled and reused eight times to prepare ethyl (2R, 3S)-2, 3-dihydroxy-3-phenylpropionate with high yield and ee via asymmetric dihydroxylation (AD) reaction.

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  • 收稿日期:  2008-11-13
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