Octopus Manganese Porphyrin with Polyglycol Chains as a Catalyst for the β-Selective Epoxidation of Cholesterol Derivatives

Run Hua LI Yuan Cong ZHAO Jiang WU Jing Song YOU Xiao Qi YU

引用本文: Run Hua LI,  Yuan Cong ZHAO,  Jiang WU,  Jing Song YOU,  Xiao Qi YU. Octopus Manganese Porphyrin with Polyglycol Chains as a Catalyst for the β-Selective Epoxidation of Cholesterol Derivatives[J]. Chinese Chemical Letters, 2004, 15(8): 915-918. shu
Citation:  Run Hua LI,  Yuan Cong ZHAO,  Jiang WU,  Jing Song YOU,  Xiao Qi YU. Octopus Manganese Porphyrin with Polyglycol Chains as a Catalyst for the β-Selective Epoxidation of Cholesterol Derivatives[J]. Chinese Chemical Letters, 2004, 15(8): 915-918. shu

Octopus Manganese Porphyrin with Polyglycol Chains as a Catalyst for the β-Selective Epoxidation of Cholesterol Derivatives

  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (No.20272039) and the Grant from the Education Ministry of China for Returnee.

摘要: Synthesis of a novel octopus porphyrin with polyglycol chains 1a was achieved.The catalytic activity of 1a's manganese complex for the epoxidation of cholesterol derivatives with PhIO give a satisfactory conversion and regioselectivity.

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  • 收稿日期:  2003-09-23
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