A NOVEL SYNTHETIC METHOD FOR THE CLUSTERS FeCo2CO9-(RCCR)(R=MeO2C,EtO2C).X-RAY CRYSTAL STRUCTURE ANALYSES OF THE CLUSTERS FeCo2CO9(MeO2CCCCO2Me)andCo4(CO)10 -(EtO2CCCCO2Et)

He Ping WU ,  Yuan Qi YIN ,  Kai Bei YU ,  Xiao Ying HUANG

引用本文: He Ping WU,  Yuan Qi YIN,  Kai Bei YU,  Xiao Ying HUANG. A NOVEL SYNTHETIC METHOD FOR THE CLUSTERS FeCo2CO9-(RCCR)(R=MeO2C,EtO2C).X-RAY CRYSTAL STRUCTURE ANALYSES OF THE CLUSTERS FeCo2CO9(MeO2CCCCO2Me)andCo4(CO)10 -(EtO2CCCCO2Et)[J]. Chinese Chemical Letters, 1996, 7(6): 585-588. shu
Citation:  He Ping WU,  Yuan Qi YIN,  Kai Bei YU,  Xiao Ying HUANG. A NOVEL SYNTHETIC METHOD FOR THE CLUSTERS FeCo2CO9-(RCCR)(R=MeO2C,EtO2C).X-RAY CRYSTAL STRUCTURE ANALYSES OF THE CLUSTERS FeCo2CO9(MeO2CCCCO2Me)andCo4(CO)10 -(EtO2CCCCO2Et)[J]. Chinese Chemical Letters, 1996, 7(6): 585-588. shu

A NOVEL SYNTHETIC METHOD FOR THE CLUSTERS FeCo2CO9-(RCCR)(R=MeO2C,EtO2C).X-RAY CRYSTAL STRUCTURE ANALYSES OF THE CLUSTERS FeCo2CO9(MeO2CCCCO2Me)andCo4(CO)10 -(EtO2CCCCO2Et)

  • 基金项目:

    This work is surported by Shanghai Organometallic Laboratory, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

摘要: A novel synthetic method for the clusters FeCo2(CO)9(RCCR)(R=MeO2C,MeO2C),which is the reaction of Co4(CO)10(RCCR) with Na2[Fe(CO)4],have been found by studying on the thermal reaction between RCCo3(CO)9 with Na2[Fe(CO)4].X-ray crystal structural determinations have been made for the clusters FeCo2(CO)9(MeO2CCCCO2Me) and Co4(CO)10(EtO2CCCCO2Et).

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  • 收稿日期:  1995-09-22
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